787-70-2, [1,1′-Biphenyl]-4,4′-dicarboxylic acid is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
In a typical preparation a solid mixture of H2BPDC (H2BPDC = 4,4′-biphenyldicarboxylic acid; 0.630 g, 2.4 mmol), bpy (bpy = 4,4′-bipyridine; 0.198 g, 1.2 mmol), and Cu(NO3)2¡¤3H2O (0.630 g, 2.4 mmol) was dissolved in a mixture of DMF (DMF = N,N’-dimethylformamide; 180 mL), pyridine (1.8 mL), and methanol (18 mL). The resulting solution was stirred at 70C for 5 min, and then distributed to 20 mL vials. The vials were then heated at 120C in an isothermal oven for 24 h. After cooling the vials to room temperature, the solid product was removed by decanting with mother liquor and washed in DMF (3 * 20 mL) for 3 days. Solvent exchange was carried out with methanol (3 * 20 mL) at room temperature for 3 days. The material was then evacuated under vacuum at 140C for 6 h, yielding 0.605 g of Cu2(BPDC)2(BPY) in the form of blue crystals, correspond to 66% based on copper., 787-70-2
787-70-2 [1,1′-Biphenyl]-4,4′-dicarboxylic acid 13084, acatalyst-ligand compound, is more and more widely used in various fields.
Reference£º
Article; Dang, Giao H.; Le, Dung T.; Truong, Thanh; Phan, Nam T.S.; Journal of Molecular Catalysis A: Chemical; vol. 400; (2015); p. 162 – 169;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI