Recommanded Product: 89972-77-0. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 4-(p-Tolyl)-2,2:6,2-terpyridine, is researched, Molecular C22H17N3, CAS is 89972-77-0, about Hexagonal terpyridine-ruthenium and -iron macrocyclic complexes by stepwise and self-assembly procedures. Author is Newkome, George R.; Cho, Tae Joon; Moorefield, Charles N.; Cush, Randy; Russo, Paul S.; Godinez, Luis A.; Saunders, Mary Jane; Mohapatra, Prabhu.
Methods for the self-assembly, as well as directed construction, of hexaruthenium metallomacrocycles, e.g., I12+, employing bis(terpyridine) building blocks are described. Self-assembly is effected by a combination of equimolar mixtures of bis-metalated and non-metalated bis(terpyridinyl) monomers each possessing the requisite planar, 60°, terpyridine-metal-terpyridine connectivity. Stepwise synthesis of the identical hexamer is also discussed and used to aid in verification of the self-assembled product. Preparation and anal. of the related FeII metallomacrocycle are detailed and its TEM image confirms the hexameric structure. Characterization of the metalated products includes cyclic voltammetry along with the routine anal. techniques.
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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI