In an article, author is Khalili, Dariush, once mentioned the application of 95-13-6, Name is Indene, molecular formula is C9H8, molecular weight is 116.1598, MDL number is MFCD00003777, category is catalyst-ligand. Now introduce a scientific discovery about this category, COA of Formula: C9H8.
Copper(I) Complex of Dihydro Bis(2-Mercapto Benzimidazolyl) Borate as an Efficient Homogeneous Catalyst for the Synthesis of 2H-Indazoles and 5-Substituted 1H-Tetrazoles
In this work, catalytic activity of a series of copper(I) complexes containing dihydrobis(2-mercapto-benzimidazolyl) borate (Bb), and phosphine co-ligands was investigated in the synthesis of N-heterocycle compounds including 2H-indazoles and 5-substituted 1H-tetrazoles. The copper(I) complex containing tricyclohexylphosphine co-ligand, [Cu(Bb)(PCy3)], displayed the highest catalytic activities for the formation of 2H-indazoles and 1H-tetrazoles. Apart from the nontoxicity and strong sigma-donating ability of the introduced ligands, the introduced catalyst required easy handling processes. The catalytic reactions were successfully performed at low catalyst loadings in either PEG-200 or DMF and in relatively short reaction times. The diversity of these reactions was also explored with 20 and 12 examples. Finally, the current catalytic system is amenable to large-scale production of these N-heterocycle compounds.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI