Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Computed Properties of CF3NaO3S, Which mentioned a new discovery about 2926-30-9
The dinuclear cation [(eta6-C6Me6)2Ru2 (mu2-H)3]+ (1) reacts in aqueous solution with hydrazine to give the dicationic complexes [(eta6-C6Me6) 2Ru2(mu2-H)2 (mu2-eta1,eta1-H2NNH2)]2+ (2) and [(eta6-C6Me6)2Ru2 (mu2-H)(mu2-eta1,eta1 -H2NNH2)(mu2-NH2)]2+ (3). The single-crystal X-ray structure analyses of 2 (tosylate salt) and 3 (triflate salt) reveal both complexes to contain an intact hydrazine ligand coordinated parallel (mu2-eta1,eta1) to the diruthenium backbone, comprising a Ru=Ru double bond (2.69 A) in 2 and a Ru-Ru single bond (2.85 A) in 3. A single crystal of the mixed sulfate-hexafluorophosphate salt of [(eta6-C6Me6)2Ru2 (mu2-H)(mu2-eta1,eta1 -H2NNH2)(mu2-N2H3)] 2+ (4), isolated from the mother liquor of 2, suggests this hydrazido complex to be an intermediate in the reaction from 2 to 3.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI