Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Formula: C10H7BrN2, Which mentioned a new discovery about 10495-73-5
The “pincer”-type carbene complexes Rh(C-N-C)Cl and Rh(C-N-N)Cl [C-N-C = 3,3?-diaryl-1,1?-pyridine-2,6-diylbis-(imidazol-2-ylidene), C-N-N = 1-aryl-3-(2,2?-bipyridin-6-yl)-imidazol-2-ylidene] have been prepared and characterised by spectroscopic and diffraction methods. They bind CO to give cationic complexes but are inert to H2. Both oxidatively add CH2Cl2 to give octahedral RhIII complexes. Theoretical calculations provide insight into the bonding of the Rh(C-N-C)Cl and Rh(C-N-N)Cl complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI