Synthetic Route of 1762-46-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1762-46-5, Name is Diethyl [2,2′-bipyridine]-5,5′-dicarboxylate, molecular formula is C16H16N2O4. In a Article,once mentioned of 1762-46-5
The Re(I) coordination compounds fac-Re(deeb)(CO)3(X), where deeb is 4,a¿²-(COOEt)2-2,2a¿²-bipyridine and X is I-, Br-, Cl-, or CN-, and [fac-Re(deeb)(CO)3(py)](OTf), where OTf- is triflate anion and py is pyridine, have been prepared, characterized, and anchored to nanocrystalline (anatase) TiO2. In regenerative solar cells with 0.5 M LiI-0.005 M I2 acetonitrile electrolyte, the Re(I) compounds convert absorbed photons into electrons efficiently. The rate of interfacial charge separation could not be time resolved, kcr > 108 s-1. Thermodynamically favorable recombination of the injected electron in TiO2 with the oxidized sensitizer requires milliseconds for completion. Charge recombination kinetics have been quantified on a 10-7-s and longer time scale and are insensitive to the Re sensitizer employed. The charge recombination kinetics have been contrasted with other sensitized TiO2 materials and are insensitive to an a¿¼960-mV change in apparent driving force. The results suggest that charge recombination is rate limited by diffusional encounters of the injected electron with the oxidized sensitizer. A 1999 American Chemical Society.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1762-46-5
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI