581-50-0, Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 581-50-0, Name is 2,3′-Bipyridine
SPECIFIC AND SELECTIVE REDUCTION OF AROMATIC NITROGEN HETEROCYCLES WITH THE BIS-PYRIDINE COMPLEXES OF BIS(1,4-DIHYDRO-1-PYRIDYL)ZINC AND BIS(1,4-DIHYDRO-1-PYRIDYL)MAGNESIUM
Aromatic nitrogen heterocycles, e.g. quinoline, 2,2′-bipyridyl and 1,10-phenanthroline, are reduced in a uniquely specific and selective way by the bis-pyridine complexes of bis(1,4-dihydro-1-pyridyl)zinc and bis(1,4-dihydro-1-pyridyl)magnesium.The reactions occur by hydrogen transfer from the metal-bound 1,4-dihydropyridyl moieties to the substrates and yield zinc or magnesium salts of the 1,4-dihydroazaaromatic derivatives.Upon hydrolysis, the 1,4-dihydroazaaromatic compounds are liberated from the metal ions.The isolation and purification of several of the (novel) reduced compounds, e.g. 1,4-dihydroquinoline and 1,4-dihydro-1,10-phenanthroline, are described.
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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI