Electric Literature of 72-19-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 72-19-5, Name is H-Thr-OH, SMILES is N[C@@H]([C@H](O)C)C(O)=O, belongs to catalyst-ligand compound. In a article, author is Ye, Xinyi, introduce new discover of the category.
Enantioselective transition metal catalysis directed by chiral cations
Enantioselective transition metal catalysis directed by chiral cations is the amalgamation of chiral cation catalysis and organometallic catalysis. Thus far, three strategies have been revealed: ligand scaffolds incorporated on chiral cations, chiral cations paired with transition metal ‘ate’-type complexes, and ligand scaffolds incorporated on achiral anions. Chiral cation ion-pair catalysis has been successfully applied to alkylation, cycloaddition, dihydroxylation, oxohydroxylation, sulfoxidation, epoxidation and C-H borylation. This development represents an effective approach to promote the cooperation between chiral cations and transition metals, increasing the versatility and capability of both these forms of catalysts. In this review, we present current examples of the three strategies and suggest possible inclusions for the future.
Electric Literature of 72-19-5, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 72-19-5 is helpful to your research.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI