Can You Really Do Chemisty Experiments About (S)-Diphenyl(pyrrolidin-2-yl)methanol

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Asymmetric synthesis of 3,3-spirooxindoles fused with cyclobutanes through organocatalytic formal [2 + 2] cycloadditions under h-bond-directing dienamine activation

The first organocatalytic asymmetric synthesis of a spirooxindole skeleton incorporated with a cyclobutane moiety has been successfully developed on the basis of H-bond-directing dienamine activation. Structurally complex spirocyclobutyl oxindoles, which possess four contiguous stereocenters, including one spiro quaternary center, were obtained in good yields (up to 83%) with excellent beta,gamma-regioselectivity (>19:1) and stereocontrol (up to >19:1 dr and 97% ee).

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI