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PROBLEM TO BE SOLVED: excellent color reproducibility, a high optical density, color tone is sharp, and discoloration of various light slamming, water resistance, moisture resistance such as dye for good fastness of the ink jet recording soln. for coloring and felt pen, or low temperature in the precipitation of the pigment in a severe environment, such as discoloration is very excellent in long-term storage without a felt pen ink jet recording liquid dye and pigment. SOLUTION: azo compound represented by the following eq. (1) or (17). ( In the formula, the respective symbols, meaning described in the claim. ) D-(A) n (1) [and 1] Selected drawing: no (by machine translation)

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Reaction of equimolar amounts of 2-aminobenzaldehyde and 3,3′-diamino-N-methyldipropylamine in methanol affords a novel 1:1 condensation product, abaMedpt, which has been isolated as the copper(II) complex, I.The crystal structure of the complex has been determined from single crystal diffractometer data and refined to a final R factor of 0.0353 with 2492 unique observations and 206 variables.The complex crystallizes in the monoclinic space group P21/c (Ndeg 14) with a = 9.263(2), b = 18.189(3), c = 11.740(3) Angstroem, beta = 92.97(4) deg, Z = 4, Dc = 1.902 g cm-3.The structure involves a five-coordinate square-pyramid CuN4I chromophore and an uncoordinated iodide anion.Nitrogen atoms constitute the basal plane, while the bonded iodine occupies the apical position.The structure contrasts with the more usual distorted trigonal-bypiramidal stereochemistries of CuN4I chromophores reported so far.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Two sensing ensembles based on the common squaramide host 2 and the acid-base indicators Cresol Red (CR) and Bromocresol Green (BG) are described. Both couples were characterized in EtOH-H2O mixtures by UV-Vis spectroscopy. Analysis of the binding curves and the corresponding Job plots indicate 1:1 binding between the indicators CR or BG and host 2. The sensing solutions are responsive to sulfate and/or phosphate anions in water, changing the coloration of the solution. As in other indicator displacement assays (IDA), host 2 translates the chemical event into a colorimetric response that is analyzed by spectrophotometry. However, since other anions present in natural waters do not result in color changes, this method allows the quantification of sulfate and phosphate in water. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2008.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Secondary squaramides have considerable potential as hydrogen bond donors and acceptors. In CHCl3 both, anti- and syn-squaramide rotamers are observed by NMR. The energetic barrier for anti/syn mutual interconversion determined by complete band shape analysis is ?63 kJ mol-1. As in proline derivatives, a low rotational barrier is crucial for the design of foldable modules. In this paper, folding based on the low rotational barrier of squaramides is driven by donor atoms (N or O) located in the gamma position of an alkyl chain of a secondary squaramide. We demonstrate that the resulting minimal module exists as a folded conformer through the formation of a nine-membered ring stabilized by intramolecular hydrogen bonding. Molecular mechanics calculations and NMR studies support the existence of these folded conformers. The intramolecularly hydrogen bonded conformers are clearly visible even in CHCl3-EtOH mixtures. Folding occurs even in pure ethanol. As an indirect test, we studied the effectiveness of macrocyclization reactions in pure ethanol that require an effective templating effect to take place. The high yields obtained support the dominant role of a folded conformer even in this solvent.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Zwitterion-containing compounds for the modification of hydrophobic molecules to improve their solubility and/or to lower their non-specific binding as provided. The zwitterion-containing compounds may be suitable for modification of detectable labels such as biotin and fluorescein to improve their solubility. The zwitterion-containing compounds may also be useful for the preparation of conjugates of proteins, peptides and other macromolecules or for crosslinking molecules and/or macromolecules.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The trinuclear complex (mu3-CO3)[Ni3(Medpt)3(NCS) 4] was obtained by reaction of basic solutions of nickel(II), Medpt (bis(3ammopropyl)methylamine) and thiocyanate ligand with atmospheric CO2 or by simple reaction with carbonate anion. (mu3-CO3)[Ni3(Medpt)3(NCS) 4] crystallizes in the triclinic system, space group P1, with a = 12.107(5) A, b = 12.535(7) A, c = 16.169(9) A, a. = 102.69(5), beta= 92.91(5), gamma = 118.01(4), Z = 2, and R = 0.043. The three nickel atoms are asymmetrically bridged by one pentadentate carbonato ligand, which shows a novel coordination mode. The (mu3-CO3)[Ni3(Medpt)3(NCS) 4] compound shows a very strong antiferromagnetic coupling. Fit as irregular triangular arrangement gave J1 = -88.4, J2 = -57.7, and J3 = -9.6 cm-1, which is the strongest AF coupling observed to date for Ni3 compounds. The magnetic behavior of the carbonato bridge is discussed.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Hairpin polyamides are high-affinity, sequence selective DNA binders. The use of a safety-catch linker for the solid phase synthesis of hairpin polyamides allows for easy preparation of derivatives ready for chemoselective ligation with unprotected peptides. Examples of ligations reported include thioether bond formation and thioester-mediated amide bond formation (‘Native Chemical Ligation’).

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Two novel macrocyclic molecular probes linked to two nitrophenylurea and two nitrophenylthiourea groups, respectively, are reported. It was found that these systems can recognize different anions (OH-, F-, CN- with the nitrophenylurea probe, and OH-, F -, CN-, CH3COO- and H 2PO4- with the nitrophenylthiourea probe) resulting in a red shift of electronic transition and correspondingly color-switching the probes. In addition, based on above sensing mechanism with the probes, IFNOT logic operations can be achieved using OH- and Cu2+ ion as inputs, and/or F- and Hg2+, respectively, making the probes, promising candidate for further applications in molecular logic devices.

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Metal catalyst and ligand design,
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Tacrine-based AChE and BuChE inhibitors were designed by investigating the topology of the active site gorge of the two enzymes. The homobivalent ligands characterized by a nitrogen-bridged atom at the tether level could be considered among the most potent and selective cholinesterase inhibitors described to date. The nitrogen-containing homobivalent ligands 3e,g and the sulfur-containing 3h validated the hypothesis of extra sites of interaction in the AChE and BuChE active site gorges.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Six dimeric 2-(2-naphthyl)quinolin-4-amines with a linker between the amino groups and eight dimeric 2-(4-anilino)quinolin-4-amines linked between the anilino groups were synthesized and evaluated for their interaction with duplex/triplex DNA’s and as antagonists of immunostimulatory oligodeoxynucleotides with a CpG-motif (CpG-ODN). The most powerful triple-helix DNA intercalator known to date, with high affinity toward T·A·T triplets and triplex/duplex selectivity, was found. The potent antagonism of immunostimulatory CpG-ODN by several bis-4-aminoquinolines is not related to their DNA interactions.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI