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Inorganic materials with controllable shapes have been an intensely studied subject in nanoscience over the past decades. Control over novel and anisotropic shapes of inorganic nanomaterials differing from those of bulk materials leads to unique and tunable properties for widespread applications such as biomedicine, catalysis, fuels or solar cells and magnetic data storage. This review presents a comprehensive overview of shape-controlled inorganic nanomaterials via nucleation and growth theory and the control of experimental conditions (including supersaturation, temperature, surfactants and secondary nucleation), providing a brief account of the shape control of inorganic nanoparticles during wet-chemistry synthetic processes. Subsequently, typical mechanisms for shape-controlled inorganic nanoparticles and the general shape of the nanoparticles formed by each mechanism are also expounded. Furthermore, the differences between similar mechanisms for the shape control of inorganic nanoparticles are also clearly described. The authors envision that this review will provide valuable guidance on experimental conditions and process control for the synthesis of inorganic nanoparticles with tunable shapes in the solution state.

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We synthesized a new quaternary ammonium salt, N-alkyl-N-2-hydroxyethyl- N,N-dimethylammonium butyl phosphate (ABP) that does not precipitate in the presence of anionic surfactants by incorporating a paired butyl phosphate anion into cationic surfactants. ABP showed much greater bactericidal activities and antirusting effects than benzalkonium chloride (BAC). In this study, the fungicidal effects of ABP were evaluated in comparison with common disinfectants [BAC, chlorhexidine digluconate (CHX) and alkyldiaminoethylglycine hydrochloride (ADE)]. Fungicidal effects were evaluated in 10 strains of 6 fungal species, namely, 3 Candida albicans, 2 Candida tropicalis, 1 Candida parapsilosis, 1 Aspergillus niger, 2 Aspergillus terreus, and 1 Trichophyton rubrum. ABP and BAC showed the same effects on 2 C. tropicalis and C. parapsilosis, and similar effects on 3 C. albicans, with slight differences among the strains. ABP showed quick fungicidal effects against A. niger and 2 A. terreus of molds in 30 min at 0.1% and in 15 min at 0.2 and 0.4%, but BAC showed slow effects against A. niger at 1 h and 2 A. terreus at 30 min at 0.2 and 0.4%, respectively. There is one factor which may have caused this difference: the former had a butyl phosphate anion and the latter had a chloride anion as a counter ion. BAC, CHX and ADE needed 24h to cause notable effects on A. niger at 0.1% and 1 h at 0.2%. The new synthetic anti-rust ABP is considered to have sufficient fungicidal effects that are comparable to those of BAC, CHX and ADE.

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Novel ammonium based hydrophobic ionic liquids (ILs) have been synthesised and characterised, and their use in the liquid-liquid extraction of uranium(vi) from an aqueous nitric acid solution using tri-n-butyl phosphate (TBP), studied. On varying the nitric acid concentration, each IL was found to give markedly different results. Relatively hydrophilic ILs showed high uranium(vi) extractability at 0.01 M nitric acid solution which progressively decreased from 0.01 to 2 M HNO3 and then increased again as the nitric acid concentration was increased to 6 M. An analysis of the mechanisms involved for one such IL, pointed to cationic-exchange being the predominant route at low nitric acid concentrations whilst at high nitric acid concentrations, anionic-exchange predominated. Strongly hydrophobic ILs showed low extractability for nitric acid concentrations below 0.1 M but increasing extractability from 0.1 M to 6 M nitric acid. The predominant mechanism in this case involved the partitioning of a neutral uranyl complex. The uranyl complexes were found to be UO22+·(TBP)3 for the cationic exchange mechanism, UO2(NO3)2(TBP) 2 for the neutral mechanism and UO2(NO3) 3-·(TBP) for the anionic exchange mechanism. The Royal Society of Chemistry 2011.

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Metal catalyst and ligand design,
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The effect of the type and the concentration of ionic surfactants on the electric charge on small silicone oil droplets is studied by using an electrical suspension method. The adsorption process of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), is characterized by gradual neutralization of the negative charge on the oil-in-water (O/W) emulsion droplets at low surfactant concentrations. As the surfactant concentration increases, the adsorption process leads to the charge reversal. The point of charge reversal (pcr) occurs approximately at 2.5 x 10-6 M CTAB. Further increasing the surfactant concentration causes an increase in the positive charge and eventually results in the maximum positive charge on the oil droplets near the critical micelle concentration (CMC) of CTAB. The limited charge reflects the saturation of the adsorption of surfactant molecules on the oil-water interface. In an anionic surfactant solution of sodium dodecyl sulphate (SDs), however, the silicone oil droplets are all negatively charged and the negative charge increases with increasing the surfactant concentration. The saturation state is also observed for the anionic surfactant adsorption. The maximum negative charge is achieved when SDs concentration approaches its CMC. In addition, two types of ionic adsorption onto the oil-water interface may occur for NaCl electrolyte solutions containing either CTAB or SDS: the surfactant adsorption and the electrolyte adsorption, although the former is much stronger than the latter. At constant surfactant concentration, their cooperation strengthens the charge at lower NaCl concentrations and leads to the strongest charge at some concentration. However, their competition at higher NaCl concentrations reduces the charge on the oil droplets. The effect of the type and the concentration of ionic surfactants on the electric charge on small silicone oil droplets is studied by using an electrical suspension method. The adsorption process of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), is characterized by gradual neutralization of the negative charge on the oil-in-water (O/W) emulsion droplets at low surfactant concentrations. As the surfactant concentration increases, the adsorption process leads to the charge reversal. The point of charge reversal (pcr) occurs approximately at 2.5×10-6 M CTAB. Further increasing the surfactant concentration causes an increase in the positive charge and eventually results in the maximum positive charge on the oil droplets near the critical micelle concentration (CMC) of CTAB. The limited charge reflects the saturation of the adsorption of surfactant molecules on the oil-water interface. In an anionic surfactant solution of sodium dodecyl sulphate (SDS), however, the silicone oil droplets are all negatively charged and the negative charge increases with increasing the surfactant concentration. The saturation state is also observed for the anionic surfactant adsorption. The maximum negative charge is achieved when SDS concentration approaches its CMC. In addition, two types of ionic adsorption onto the oil-water interface may occur for NaCl electrolyte solutions containing either CTAB or SDS: the surfactant adsorption and the electrolyte adsorption, although the former is much stronger than the latter. At constant surfactant concentration, their cooperation strengthens the charge at lower NaCl concentrations and leads to the strongest charge at some concentration. However, their competition at higher NaCl concentrations reduces the charge on the oil droplets.

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Diasporic bauxite represents one of the major aluminum resources. Its upgrading for further processing involves a separation of diaspore (the valuable mineral) from aluminosilicates (the gangue minerals) such as kaolinite, illite, and pyrophyllite. Flotation is one of the most effective ways to realize the upgrading. Since flotation is a physicochemical process based on the difference in the surface hydrophobicity of different components, determining the adsorption characteristics of various flotation surfactants on the mineral surfaces is critical. The surfactant adsorption properties of the minerals, in turn, are controlled by the surface chemistry of the minerals, while the latter is related to the mineral crystal structures. In this paper, we first discuss the crystal structures of the four key minerals of diaspore, kaolinite, illite, and pyrophyllite as well as the broken bonds on their exposed surfaces after grinding. Next, we summarize the surface chemistry properties such as surface wettability and surface electrical properties of the four minerals, and the differences in these properties are explained from the perspective of mineral crystal structures. Then we review the adsorption mechanism and adsorption characteristics of surfactants such as collectors (cationic, anionic, and mixed surfactants), depressants (inorganic and organic), dispersants, and flocculants on these mineral surfaces. The separation of diaspore and aluminosilicates by direct flotation and reverse flotation are reviewed, and the collecting properties of different types of collectors are compared. Furthermore, the abnormal behavior of the cationic flotation of kaolinite is also explained in this section. This review provides a strong theoretical support for the optimization of the upgrading of diaspore bauxite ore by flotation and the early industrialization of the reverse flotation process.

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Metal catalyst and ligand design,
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Noble metal nanoparticles have been extensively studied to understand and apply their plasmonic responses, upon coupling with electromagnetic radiation, to research areas such as sensing, photocatalysis, electronics, and biomedicine. The plasmonic properties of metal nanoparticles can change significantly with changes in particle size, shape, composition, and arrangement. Thus, stabilization of the fabricated nanoparticles is crucial for preservation of the desired plasmonic behavior. Because plasmonic nanoparticles find application in diverse fields, a variety of different stabilization strategies have been developed. Often, stabilizers also function to enhance or improve the plasmonic properties of the nanoparticles. This review provides a representative overview of how gold and silver nanoparticles, the most frequently used materials in current plasmonic applications, are stabilized in different application platforms and how the stabilizing agents improve their plasmonic properties at the same time. Specifically, this review focuses on the roles and effects of stabilizing agents such as surfactants, silica, biomolecules, polymers, and metal shells in colloidal nanoparticle suspensions. Stability strategies for other types of plasmonic nanomaterials, lithographic plasmonic nanoparticle arrays, are discussed as well.

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Metal catalyst and ligand design,
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The paper focuses on the simple separation of reactive acid dyes dissolved in aqueous solution using low-melting quaternary ammonium salts (ionic liquids). The effect of bulkiness of quaternary ammonium cations added in the form of readily applicable ionic liquids on the removal efficiency was studied. Especially benzyldimethylhexadecylammonium chloride combines acceptable aqueous solubility and high removal efficiency for all tested dyes. Rapid removal of dyes Reactive Orange 16, Reactive Blue 4, Reactive Orange 12, Reactive Black 5 and Reactive Black 39 from diluted aqueous solution was successfully tested using cheap and readily commercially available ionic liquid benzalkonium chloride as substitute of expensive benzyldimethylhexadecylammonium chloride liquid ion exchanger with co-action of inorganic coagulant (Al(III) or Fe(III) sulfate. The obtained removal efficiency of tested dyes from model aqueous solutions using aqueous mixture of 0.1 mol L-1 benzalkonium chloride and 0.4 mol L-1 Al2(SO4)3 is higher than 88 %, in most cases over 97 %.The removal efficiency of benzalkonium chloride mixed with aqueous Fe2(SO4)3 is less effective.

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Metal catalyst and ligand design,
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Local ocular delivery of cyclosporine A (CsA) is the preferred method for CsA delivery as a treatment for ocular inflammatory diseases such as uveitis, corneal healing, vernal keratoconjunctivitis and dry eye disease. However, due to the large molecular weight and hydrophobic nature of CsA and the natural protective mechanisms of the eye, achieving therapeutic levels of CsA in ocular tissues can be difficult. This review gives a comprehensive overview of the current products available to clinicians as well as emerging drug delivery solutions that have been developed at both the academic and industry levels.

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Metal catalyst and ligand design,
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Nanocolloidal dispersion of silver chloride was successfully synthesized in aqueous medium using three different cationic surfactants. In the one pot synthesis, surfactant molecules served dual purposes: they acted as the source for the chloride ion as well as the capping agents. Formation of the surfactant stabilized nanoparticle was established from Raman spectra. Surfactant molecules stabilized the nanoparticles through the formation of a double layer like structure. Surfactant stabilized growth process for the nanoparticles followed first order kinetics as revealed from the quasi-elastic light scattering measurement. Size and morphology of the particles were found to be dependent on the concentration of silver ion as well as the surfactant head group. A catalytic amount of silver chloride nanoparticle degraded the carcinogenic dye pinacyanol chloride. Antibacterial activity of AgCl nanoparticle was assessed using a gram positive bacteria, Bacillus subtilis.

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This invention relates to an anti-microbial composition comprising: (i) a compound of formula: [N(CH3)3Q2]+Y- (C2) wherein Q2 has structure ?(CH2)aNHC(O)(CH2)bCHCH2, wherein a + b is an integer of from 8 to 18, provided that a and b are each independently an integer of from 1 to 9, wherein Y- is a halide anion, alkylsulphate, sulphonate, saccharinate, or bicarbonate, or a mixture of compounds of formula (C2); (ii) at least one anti-microbial quaternary ammonium compound and chlorhexidine or a chlorhexidine salt; and (i) a polar solvent. In particular, the invention relates to anti-microbial compositions that can be used on skin.

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