13510-35-5, Indium(III) iodide is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: In a 500 mL round bottom flask with a gas in- and outlet, AlCl3 (99.998 % from AlfaAesar, 50.0 g, 375 mmol) was suspended in toluene (approximately 250 mL). The flask was exposed to a pressure of PH3 until the pressure gauge read 1800 hPa under vigorous stirring. Upon formation of the CI3AI-PH3 adduct, the pressure drops and eventually the procedure has to be repeated until a clear solution is obtained and no AlCb remains undissolved in the vessel. The reaction mixture was stirred for another 30 min under PEb and then purged to the quenching system. To remove excess PEb from the solution, the flask was flushed with argon for 15 min under vigorous stirring. Toluene was added to the flask to obtain a total volume of 375 mL and thus, a 1.0 M stock solution of the CbAl-PEb adduct. 31P-NMR (101 MHz, toluene): d = -168.7 (q, PH = 374.5 Hz) ppm.
The synthetic route of 13510-35-5 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; ETH ZURICH; GRUeTZMACHER, Hansjoerg; BISPINGHOFF, Mark; (62 pag.)WO2019/175319; (2019); A1;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI