Brief introduction of N,N,N-Trimethyldecan-1-aminium bromide

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Preparation of nanospheres from oxidised cellulose nanofibrils via polyelectrolyte complexation

Cellulose consists of both crystalline and amorphous region. The amorphous regions are cut down when disturbed, with only the remaining crystalline regions consisting of nanometer size. The TEMPO specific oxidation of cellulose fibre provides carboxylated cellulose nano-crystals. The surface carboxylated cellulose was prepared by TEMPO-mediated specific oxidation method. Supernatant of the reaction mass contains oxidised cellulose nanofibrils that were isolated. The anionic cellulose nanocrystals were enabled to undergo polyelectrolyte complexation with cationic polymers. The nano-spheres were prepared from oxidised cellulose through polyelectrolyte complexation with chitosan in different concentrations. The shape of the nano-sphere was identified by SEM. The nano-spheres were agglomerate on excess chitosan. To overcome that, the surface was hydrophobically modified with alkyl tail. The hydrophobic modification was given individual nano-spheres and they were distinctly identified. This communication will derive a new nanomaterial of CNF, which will act as a nano carrier for delivery applications.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Molecules to Enhance Percutaneous Delivery and Methods for Discovery Therefor

An IR spectroscopic technique provides methods for measuring the irritation potential of a formulation and to assess the ability of molecules to enhance the permeability of substances into and through skin using samples comprising stratum corneum. Molecules are screened for their performance as chemical penetration enhancers using a unique in silico procedure that may be applied iteratively in an attempt to generate molecules showing successively higher performance. Both the irritation potential and the ability of the molecule to enhance penetration are considered in the in silico approach. The invention provides specific molecules that may be used in topical or transdermal formulations to improve the delivery of actives. The structures of compounds of the invention include: Formulas (I), (II), (III), (IV), (V), (IV) and analogs thereof.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Temperature and concentration effects on decyltrimethylammonium micelles in water

Wide-angle neutron scattering experiments combined with Empirical Potential Structural Refinement modelling have been used to study the detailed structure of decyltrimethylammonium bromide (C10TAB) micelles at two different temperatures; 25C and 50C and two concentrations; 0.4 and 0.8 M in water. At higher temperature, the micelles become smaller, and fewer counterions bind to the micelle surfaces, however, the headgroup positions are more ordered, possibly due to crowding in the smaller micelles. At higher concentration, the models suggest the micelles become elongated, although the aggregations numbers are smaller than those at the lower concentration. The smaller micelles found in 0.8 M solutions have more hydrated headgroups and lower counterion binding than the ellipsoidal micelles found in 0.4 M C10TAB solutions.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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MOLECULES TO ENHANCE PERCUTANEOUS DELIVERY AND METHODS FOR DISCOVERY THEREFOR

An IR spectroscopic technique provides methods for measuring the irritation potential of a formulation and to assess the ability of molecules to enhance the permeability of substances into and through skin using samples comprising stratum corneum. Molecules are screened for their performance as chemical penetration enhancers using a unique in silico procedure that may be applied iteratively in an attempt to generate molecules showing successively higher performance. Both the irritation potential and the ability of the molecule to enhance penetration are considered in the in silico approach. The invention provides specific molecules that may be used in topical or transdermal formulations to improve the delivery of actives. The structures of compounds of the invention include: Formulas (I), (II), (III), (IV), (V), (IV) and analogs thereof.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Heat Capacities of Aqueous Decyl-, Dodecyl-, Tetradecyl-, and Hexadecyltrimethylammonium Bromides at 10, 25, 40, and 55 deg C

We have used a flow microcalorimeter and a vibrating-tube densimeter to measure heat capacities and densities of aqueous solutions of decyltrimethylammonium bromide, dodecyltrimethylammonium bromide, tetradecyltrimethylammonium bromide, and hexadecyltrimethylammonium bromide at 10, 25, 40, and 55 deg C.We have calculated apparent molar heat capacities from the measured heat capacities.From the temperature dependence of parameters obtained from previously measured enthalpy data, we have derived relative apparent molar heat capacities.The apparent molar heat capacities calculated from our measurements are consistent within experimental error with those calculated from the enthalpy data.The application of simple thermodynamic relationships has allowed us to combine the apparent molar heat capacities and the relative apparent molar heat capacities to obtain <*> values for each surfactant at each temperature.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Osmotic Coefficients of Alkyltrimethylammonium Bromides in Water and in Aqueous Sodium Bromide Solutions at 55 deg C

We have measured osmotic coefficients of aqueous solutions of decyltrimethylammonium bromide, dodecyltrimethylammonium bromide, tetradecyltrimethylammonium bromide, and hexadecyltrimethylammonium bromide at 55 deg C and at cocncentrations ranging from 0.01 to 0.30 m.The measurements were made with a vapor pressure osmometer/molecular weight apparatus.We have also measured the osmotic coefficients of aqueous mixtures of sodium bromide and these same surfactants.The ratio of molalities of surfactant to added salt was held constant at 1:1.A mass-action model that inclludes activity coefficients all species in solution was used to analyze the data.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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ELECTROLYTE AND ITS USE FOR THE DEPOSITION OF BLACK RUTHENIUM COATINGS AND COATINGS OBTAINED IN THIS WAY

The invention relates to a ruthenium electrolyte which is suitable for the deposition of decorative and industrial layers having a particular blackness. The invention further relates to the use of the electrolyte of the invention in a process for the deposition of decorative and industrial layers of ruthenium having a particular blackness (?black ruthenium) on jewelry, decorative goods, consumer goods and industrial articles. The invention therefore likewise relates to corresponding layers and the articles coated in this way. The electrolyte is characterized in that it operates in the weakly acidic to alkaline pH range.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Interfacial area evaluation in a bubble column in the presence of a surface-active substance. Comparison of methods

The influence of a surface-active substance upon the behaviour observed for the gas-liquid interfacial area in a bubble column has been studied employing two different techniques: chemical and photographic methods. Important differences between the interfacial area values have been found, and they have been assigned to different phenomena existing in this kind of systems, especially the Marangoni and barrier effect. The experimental results obtained in this work under different operational conditions imply that the chemical method is greatly influenced by the existence of surface tension gradients, and this phenomenon produces high values for the interfacial area.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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ELECTROLYTE AND ITS USE FOR THE DEPOSITION OF BLACK RUTHENIUM COATINGS AND COATINGS OBTAINED IN THIS WAY

The invention relates to a ruthenium electrolyte which is suitable for the deposition of decorative and industrial layers having a particular blackness. The invention further relates to the use of the electrolyte of the invention in a process for the deposition of decorative and industrial layers of ruthenium having a particular blackness (?black ruthenium) on jewelry, decorative goods, consumer goods and industrial articles. The invention therefore likewise relates to corresponding layers and the articles coated in this way. The electrolyte is characterized in that it operates in the weakly acidic to alkaline pH range.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Interfacial area evaluation in a bubble column in the presence of a surface-active substance. Comparison of methods

The influence of a surface-active substance upon the behaviour observed for the gas-liquid interfacial area in a bubble column has been studied employing two different techniques: chemical and photographic methods. Important differences between the interfacial area values have been found, and they have been assigned to different phenomena existing in this kind of systems, especially the Marangoni and barrier effect. The experimental results obtained in this work under different operational conditions imply that the chemical method is greatly influenced by the existence of surface tension gradients, and this phenomenon produces high values for the interfacial area.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI