Some scientific research about N,N,N-Trimethyldecan-1-aminium bromide

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Hexafluoroisopropanol-Based Deep Eutectic Solvent/Salt Aqueous Two-Phase Systems for Extraction of Anthraquinones from Rhei Radix et Rhizoma Samples

Deep eutectic solvents (DESs), a new class of green and sustainable solvents, have shown a promising application prospect in the aqueous two-phase system (ATPS) extraction. In the present work, hexafluoroisopropanol (HFIP) was introduced as a hydrogen-bond donor to synthesize DESs with choline chloride (ChCl), decyltrimethylammonium bromide, dodecyltrimethylammonium bromide, and tetradecyltrimethylammonium bromide (hydrogen-bond acceptor), respectively. These HFIP-based DESs (HFIP-DESs) can form ATPS with various inorganic salts, and their phase separation ability is significantly stronger than that of small molecule aliphatic alcohols, HFIP, and traditional DESs. The ATPSs based on HFIP-DESs were first used to extract anthraquinones (AQs) from Rhei Radix et Rhizoma samples. Under the optimal conditions, more than 92% of AQs (including aloe-emodin, rhein, emodin, chrysophanol, and physcion) was enriched in the DES-rich phase of the ATPS composed of ChCl-HFIP DES and Na2SO4. Compared with the traditional chloroform extraction method (60 mL chloroform consumption), the ChCl-HFIP DES/Na2SO4 ATPS extraction method attained high extraction efficiency but only consumed 0.5 mL of organic solvent (HFIP).

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

The important role of N,N,N-Trimethyldecan-1-aminium bromide

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New 4-amino-N-alkylphthalimides as fluorescence probes for beta-cyclodextrin inclusion complexes and hydrophobic microdomains of amphiphilic systems

The synthesis and photophysical behaviour of a series of 4-amino-N-alkylphthalimides have been described. The complexation between beta-cyclodextrin and the different phthalimides has been studied by steady-state fluorescence. The association constant K depends strongly on the hydrophobicity of the alkyl substituent, and the K values vary between 115 M-1 and 19,000 M-1. The studied compounds have been used as fluorescent probes to determine the first and second association constants of surfactants with beta-cyclodextrin from competitive binding data. The results are compared with those given by other authors, and limitations of the method are discussed. 4-Amino-N-tert-butylphthalimide is also used as a sensor for following micellar aggregation process of surfactants and autoassociation of hydrophobically modified polymers. Values of critical micellar concentration (cmc) and critical aggregation concentration (cac) are determined, and comparison is made with pyrene.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 2082-84-0, molcular formula is C13H30BrN, introducing its new discovery. name: N,N,N-Trimethyldecan-1-aminium bromide

Interactions of hyaluronan with oppositely charged surfactants in very diluted solutions in water

The phase behavior of aqueous systems containing hyaluronan, at concentrations between 2 and 100 mg/L, and oppositely charged surfactants was investigated. A fluorescence probe technique revealed the formation of micellar structures on the hyaluronan in homogeneous systems well below the surfactant standard, critical, micellar concentration. Moreover, regions of gel-phase separation were revealed. A detailed phase diagram was, thus, constructed in the very diluted region and the hyaluronan concentration was found to be the main parameter controlling the phase behavior, in contrast to the charge ratio. The stability of hyaluronan-surfactant aggregates in the homogeneous systems while in storage at 4 C (up to three months), against dilution, salt addition and on heating-cooling (between 10 and 50 C) was also investigated. The aggregates were stable while in storage or upon increasing and decreasing the temperature. The dilution of hyaluronan-surfactant complexes or the addition of 0.15 M NaCl led to their disintegration. Finally, systems prepared in a 0.15 M NaCl solution showed that interactions are suppressed and no aggregation below the standard critical micellar concentration was observed.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Electric Literature of 2082-84-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.2082-84-0, Name is N,N,N-Trimethyldecan-1-aminium bromide, molecular formula is C13H30BrN. In a Article£¬once mentioned of 2082-84-0

Functionalization of MXene nanosheets for polystyrene towards high thermal stability and flame retardant properties

Fabricating high-performance MXene-based polymer nanocomposites is a huge challenge because of the poor dispersion and interfacial interaction of MXene nanosheets in the polymer matrix. To address the issue, MXene nanosheets were successfully exfoliated and subsequently modified by long-chain cationic agents with different chain lengths, i.e., decyltrimethylammonium bromide (DTAB), octadecyltrimethylammonium bromide (OTAB), and dihexadecyldimethylammonium bromide (DDAB). With the long-chain groups on their surface, modified Ti3C2 (MXene) nanosheets were well dispersed in N,N-dimethylformamide (DMF), resulting in the formation of uniform dispersion and strong interfacial adhesion within a polystyrene (PS) matrix. The thermal stability properties of cationic modified Ti3C2/PS nanocomposites were improved considerably with the temperatures at 5% weight loss increasing by 20 C for DTAB-Ti3C2/PS, 25 C for OTAB-Ti3C2/PS and 23 C for DDAB-Ti3C2/PS, respectively. The modified MXene nanosheets also enhanced the flame-retardant properties of PS. Compared to neat PS, the peak heat release rate (PHRR) was reduced by approximately 26.4%, 21.5% and 20.8% for PS/OTAB-Ti3C2, PS/DDAB-Ti3C2 and PS/DTAB-Ti3C2, respectively. Significant reductions in CO and CO2 productions were also obtained in the cone calorimeter test and generally lower pyrolysis volatile products were recorded by PS/OTAB-Ti3C2 compared to pristine PS. These property enhancements of PS nanocomposites are attributed to the superior dispersion, catalytic and barrier effects of Ti3C2 nanosheets.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The Interactions of Methylated Ammonium Ions in Lyotropic Liquid Crystalline Solution

The mono-, di- and trimethylammonium ions have been investigated in the lyotropic liquid crystalline system of potassium dodecanoate/alkyltrimethylammonium bromide.The results indicate that non-bonded forces deriving from the anisotropy of the medium contribute little to the alignment of these ions but that forces deriving from binding of the ions to the dodecanoate headgroups provide the major mechanism for the imposition of alignment.A three-site model of ion binding was found to be sufficient to describe the change in dipolar couplings as the micellar surface change was varied.It is also found that anomalous changes in ratios of coupling constants were accounted for by the three site model of binding. – Keywords: lyotropic; mesophase; ion binding; ammonium; nematic.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Micellar formation of cationic surfactants

The micellar structure of six alkyl trimethylammonium halides was studied via conductivity. It was found that the aggregation number increased with the decreasing carbon chain length. Furthermore, Br? significantly enhanced the micellar formation over Cl?. However, the aggregation number and ionization degree remain similar for both anions. The modelling results validate that the counter-anions affect micellar formation via equilibrium constants, instead of their hydration size. In particular, the association constants between surfactant (both monomer and micelle) and Br? are significantly higher than Cl?. This is consistent with the qualitative description of hydrated Br? in the literature. The experimental and modelling results confirm that micelles are formed via ?ion-paring/hydration? structure, instead of the conventional ?packing? concept.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Simple exploration of N,N,N-Trimethyldecan-1-aminium bromide

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Effects of hydrophobic modification of chitosan and Nafion on transport properties, ion-exchange capacities, and enzyme immobilization

This research compares the mass transport and ion-exchange properties of two hydrophobically modified micellar polymers, chitosan and Nafion. It was shown that hydrophobically modified micellar polymers alter the transport properties of redox species to the electrode surface as a function of the size and charge of the redox species. This research details the first use of hydrophobically modified chitosan to modify electrode surfaces, along with evidence that oxidoreductase enzymes can be effectively immobilized in the polymers while maintaining enzymatic activity. Glucose oxidase was immobilized within the hydrophobically modified chitosan and the resulting enzyme activity was compared to buffer measurements and immobilization within hydrophobically modified Nafion. It was shown that the increase in hydrophobicity increases the enzyme activity, resulting in a more optimal membrane for enzyme immobilization.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Brief introduction of N,N,N-Trimethyldecan-1-aminium bromide

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 2082-84-0, help many people in the next few years.COA of Formula: C13H30BrN

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Recent progress on nanostructured conducting polymers and composites: synthesis, application and future aspects

Conducting polymers (CPs) have been widely investigated due to their extraordinary advantages over the traditional materials, including wide and tunable electrical conductivity, facile production approach, high mechanical stability, light weight, low cost and ease in material processing. Compared with bulk CPs, nanostructured CPs possess higher electrical conductivity, larger surface area, superior electrochemical activity, which make them suitable for various applications. Hybridization of CPs with other nanomaterials has obtained promising functional nanocomposites and achieved improved performance in different areas, such as energy storage, sensors, energy harvesting and protection applications. In this review, recent progress on nanostructured CPs and their composites is summarized from research all over the world in more than 400 references, especially from the last three years. The relevant synthesizing experiences are outlined and abundant application examples are illustrated. The approaches of production of nanostructured CPs are discussed and the efficacy and benefits of newest trends for the preparation of multifunctional nanomaterials/nanocomposites are presented. Mechanism of their electrical conductivity and the ways to tailor their properties are investigated. The remaining challenges in developing better CPs based nanomaterials are also elaborated.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 2082-84-0, help many people in the next few years.Formula: C13H30BrN

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Mxene functionalized polymer composites: Synthesis and applications

Ever since their inception, Mxene have been gathering immense attention due to their exceptional and functional properties owing to their large surface areas and electronic properties. Mxene are derived from MAX phase by exfoliating them into 2D layers of transition-metal carbide and nitrides, using hydrofluoric acid (HF) solutions and sonication. Although the applications of Mxene are limited, numerous composites of Mxene filled with potential scientific and technological applications are being synthesized around the world. Several composites of Mxene like carbon nanotubes, graphene oxide etc. have been studied over the years for high capacity energy storage but these composites sometimes lack various structural and biological properties which steers research towards more flexible solutions, literally and figuratively. Polymers are a great choice for synthesizing composites of Mxene due to their versatility, compatibility and cost. As wearable technology gains popularity, MXene coated polymers emerged as a solution, delivering exceptional flexibility, mechanical and tensile strength in the form of flexible super capacitors. Focussing on the polymer composites of Mxene, this review provides a comprehensive categorical view based on application on the various polymer composites synthesized till date highlighting their promising potential in various fields of science with a vision of their future applications.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Thermodynamic and interfacial properties of binary cationic mixed systems

The critical micelle concentration of a binary mixture of C 12-C16 triphenylphosphonium bromides with decyltrimethylammonium bromide was determined as a function of temperature employing conductometric titration to evaluate the thermodynamic properties of self-assembly. Using surface tensiometry, the thermodynamics of adsorption, surface excess, and the minimum area occupied by surfactant molecules were also evaluated. Results were analyzed using regular solution theory (RST) to obtain the composition of the mixed micelles and the interaction parameter, betam, to evaluate the type and strength of interactions of surfactants in the mixed micelle. Activity coefficients and excess free energy of mixing were also determined.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI