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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 22426-14-8, name is 2-Bromo-1,10-phenanthroline, introducing its new discovery. COA of Formula: C12H7BrN2

A mild method for the regioselective C2-bromination of fused azine N-oxides is presented, employing tosic anhydride as the activator and tetra-n-butylammonium bromide as the nucleophilic bromide source. The C2-brominated compounds are produced in moderate to excellent yields and with excellent regioselectivity in most cases. The potential extension of this method to other halogens, effecting C2-chlorination with Ts2O/TBACl is also presented. Finally, this method could be incorporated into a viable one-pot oxidation/bromination process, using methyltrioxorhenium/urea hydropgen peroxide as the oxidant.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The present invention refers to at least one aromatic ring substituted with at least one linker moiety phenanthroline subbands with which it is connected via organic compounds having aryl, including organic light emitting diode and an organic light emitting display device to same are disclosed. The present invention according to organic compounds include electron transfer characteristics and thermal stability, alkali metal and alkaline earth metal compound and a stable gap stay seat formed on the substrate. The present invention according to organic compounds and/or tandem structure of barrier using reductive dopant charge creation layer in organic light emitting diodes, light emitting efficiency is improved in which life can be wave. (by machine translation)

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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A novel, simple and practical method for the regioselective halogenation of fused heterocyclic N-oxides has been developed. It employs Vilsmeier reagent, generated in situ by POX3and DMF, as both the activating agent and the nucleophilic halide source. The method is amenable across a broad range of substrates, including quinolines, isoquinolines and the diazine N-oxides, possessing a variety of substitution patterns. Furthermore, all of the reagents associated are cheap and easy to obtain. The potential extension of this method to a one-pot oxidation/halogenation sequence that obviates the need for isolation of the N-oxide intermediates is also presented.

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Metal catalyst and ligand design,
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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 22426-14-8, molcular formula is C12H7BrN2, introducing its new discovery. category: catalyst-ligand

The organic application of prolonging the life, efficiency, markedly improves the electrochemical stability and thermal stability can be heterocyclic compound, and said heterocyclic compound contained in the organic compound layer organic light emitting device number under public affairs substrate. (by machine translation)

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Metal catalyst and ligand design,
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The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 22426-14-8 is helpful to your research. Computed Properties of C12H7BrN2

In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 22426-14-8, name is 2-Bromo-1,10-phenanthroline, introducing its new discovery. Computed Properties of C12H7BrN2

We have described herein a series of unsymmetric 1,10-phenanthroline (phen) based aromatic heterocyclic derivatives with triphenylamine (TPA) and thiophene donors (L1-L5) and their respective neutral tricarbonyl rhenium(I) complexes (6a-6e). Comparisons between isomeric compounds L1/L2 and 6a/6b as well as L3/L4/L5 and 6c/6d/6e have been made on their 1H NMR and UV/Vis spectra, single-crystal structures and density function theory (DFT) calculations. The alterations of conjugated system of the whole molecules, originating from the introduction of 2-, 3- or 3,8-substituted TPA and thiophene groups of phen, are responsible for the structural and spectral discrepancy of these structural isomers. In particular, the introduction of TPA and/or thiophene donors at 2-postion of phen (L1 and L3) leads to smaller band gaps than their respective 3-substituted isomers (L2 and L4). In addition, rhenium(I) ion complexation could slightly lower the highest occupied molecular orbital (HOMO) energy levels but significantly decrease the lowest unoccupied molecular orbital (LUMO) energy levels of the molecular system.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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The present invention provides a novel double-polar light emitting body material, said double-polarity light-emitting host material of the structural formula is: , Wherein Q1 For the H atom, a halogen atom, the carbon atom number is 1 – 12 alkyl, aryl, conjugated heterocyclic, alkoxyl group or in any one of the cyanogen groups and bases; Q2 For the H atom, a halogen atom, the carbon atom number is 1 – 12 alkyl, aryl, conjugated heterocyclic, alkoxyl group or in any one of the cyanogen groups and bases. The invention also provides the dual-polarity light-emitting host material of the synthetic method and preparing the organic light-emitting device of the application. The synthetic method is simple, the obtained double-polar light emitting body material with 1, 10 – phenanthrene structure and triphenylene structural characteristic, by introducing more balanced group, can be further balanced electronic transport rate with the electron transportation, applied to the light-emitting device in the electron transportation rate can be improved, thereby improving the luminous efficiency of the light emitting device. (by machine translation)

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Reaction of KHS with 2-chloro and 2,9-dichloro-1,10-phenanthroline in ethanol at elevated temperature and pressure afforded the corresponding phenanthrolinethiols which were characterized by spectroscopic and chemical methods. 2,2′-Thiobis(1,10-phenanthroline) and other heteroaryl sulfides derived from 1,10-phenanthroline-2-thiol were prepared by amide promoted nucleophilic substitution of aryl halide by thiolate anion.

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Metal catalyst and ligand design,
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An organic light emitting display device is provided. The organic light emitting display device includes at least two or more light emitting parts each having a light emitting layer and an electron transport layer; and a charge generation layer between the at least two or more light emitting parts. The charge generation layer comprises a compound that includes a core with two nitrogen atoms and a functional group having crystallinity.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: 2-Bromo-1,10-phenanthroline. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 22426-14-8

Bifunctional Ru(II) complex catalysed carbon-carbon bond formation: an eco-friendly hydrogen borrowing strategy

The atom economical borrowing hydrogen methodology enables the use of alcohols as alkylating agents for selective C-C bond formation. A bifunctional 2-(2-pyridyl-2-ol)-1,10-phenanthroline (phenpy-OH) based Ru(ii) complex (2) was found to be a highly efficient catalyst for the one-pot beta-alkylation of secondary alcohols with primary alcohols and double alkylation of cyclopentanol with different primary alcohols. Exploiting the metal-ligand cooperativity in complex 2, several aromatic, aliphatic and heteroatom substituted alcohols were selectively cross-coupled in high yields using significantly low catalyst loading (0.1 mol%). An outer-sphere mechanism is proposed for this system as exogenous PPh3 has no significant effect on the rate of the reaction. Notably, this is a rare one-pot strategy for beta-alkylation of secondary alcohols using a bifunctional Ru(ii)-complex. Moreover, this atom-economical methodology displayed the highest cumulative turn over frequency (TOF) among all the reported transition metal complexes in cross coupling of alcohols.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME

The specification is compound and including organic electronic devices are disclosed. (by machine translation)

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI