485-71-2, Cinchonidine is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
The modification of CD and the subsequent later hydroxylationwere performed as reported in our previous works [26,27]. Briefly,an ice-cooled solution of CD in THF containing TEA was added drop-wise to the TMCS. The reaction mixture was stirred for 20 h at roomtemperature and then for 2 h at 60C. The product was extractedwith chloroform and washed with water. The obtained productwas hydrosilated with the Pt(COD)Cl2catalyst precursor and TMS(TMS/catalyst = 120 mol ratio) at 40C, using toluene as the sol-vent. The reaction mixture was stirred for 5 h at 90C under a N2atmosphere. Purification was performed by flash chromatography(hexane-acetone-TEA = 40:18:1).
485-71-2, 485-71-2 Cinchonidine 101744, acatalyst-ligand compound, is more and more widely used in various fields.
Reference£º
Article; Campos, Cristian H.; Torres, Cecilia C.; Osorio-Vargas, Paula; Mella, Claudio; Belmar, Julio; Ruiz, Doris; Fierro, Jose L.G.; Reyes, Patricio; Journal of Molecular Catalysis A: Chemical; vol. 398; (2015); p. 190 – 202;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI