Properties and Exciting Facts About N,N,N-Trimethyl-1-phenylmethanaminium bromide

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Luminescent manganese(II) complexes: Synthesis, properties and optoelectronic applications

Luminescent manganese(II) complexes have been extensively studied owing to their excellent photophysical properties. The facile synthesis and tunable optoelectronic performance of manganese(II) complexes render them attractive candidates for developing low-cost organic light-emitting diodes, information storage and security, as well as opto-electronic switches. In this review, we focus on the material category and synthesis, luminesDiverse optoelectronic applications of luminescent manganese complex are cence process, and various luminescent properties of manganese(II) complexes, together with their applications in functional devices. Finally, the challenge and outlook on the future research for manganese(II) complexes are given.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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[Fe3Cu(SPri)6Cl3]2-: A novel mixed-metal thiolate complex with a ‘truncated’ adamantane-like structure

Reaction of [Fe2(SPri)6]2- with FeCl2 and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)6Cl3]2- which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution 1H NMR spectrum are reported.

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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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METHOD FOR PRODUCING 2-OXO-1-PHENYL-3-OXABICYCLO[3.1.0]HEXANE

Disclosed is a method for producing 2-oxo-1-phenyl-3-oxabicyclo[3.1.0]hexane comprising a step for reacting phenyl acetonitrile with epichlorohydrin in the presence of sodium hydride. With this method, 2-oxo-1-phenyl-3-oxabicyclo[3.1.0]hexane can be produced safely, simply and commercially advantageously.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure-Stability Relationships

Highly base-stable cationic moieties are a critical component of anion exchange membranes (AEMs) in alkaline fuel cells (AFCs); however, the commonly employed organic cations have limited alkaline stability. To address this problem, we synthesized and characterized the stability of a series of imidazolium cations in 1, 2, or 5 M KOH/CD3OH at 80 C, systematically evaluating the impact of substitution on chemical stability. The substituent identity at each position of the imidazolium ring has a dramatic effect on the overall cation stability. We report imidazolium cations that have the highest alkaline stabilities reported to date, >99% cation remaining after 30 days in 5 M KOH/CD3OH at 80 C.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Water-soluble aminocalix[4]arene receptors with hydrophobic and hydrophilic mouths

We report the new water-soluble aminocalix[4]arene hosts 1 and 2 with deep hydrophobic cavity facilitating hydrophobic mouth and hydrophilic mouth, respectively. The 1H NMR titrations revealed that host 1 shows high selectivity for neutral guests 9 and 10, with log K of 4.2 and 4.6, respectively. The host 2 shows log K of 4.9 for binding with guest 15. Moreover, the binding ability of the host 2 for guest 14 is stronger by a factor of 1000 than that of the host 1.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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New supraicosahedral metallacarboranes. The synthesis and molecular structures of 4-dppe-4,1,6-closo-NiC2B10H12 and [4-(eta-C3H5)-4-(CO)2-4,1,6-closo-MoC 2B10H12]-

The new 13-vertex nickelacarborane 4-dppe-4,1,6-closo-NiC2B10H12 and molybdacarborane [4-(eta-C3H5)-4-(CO)2-4,1,6-closo-MoC 2B10H12]- have been prepared. The structure of the CH2Cl2 solvate of the nickel species has been studied as two crystalline modifications. The molybdacarborane was also studied crystallographically as its [PhCH2NMe3]+ salt. The differing trans influences of C and B atoms in the metalla-bonded C2B4 carborane ligand face are used to rationalise the difference in Ni-P distances in the nickelacarborane and the orientation of the {Mo(C3H5)(CO)2} fragment in the molybdacarborane. Both metallacarboranes display fluxionality in solution at room temperature which can be arrested by cooling. An activation energy for the presumed double diamond-square-diamond fluxional process is calculated to be ca. 47 kJ mol-1 by analysis of the 1H and 31P NMR spectra of the nickelacarborane. For the molybdacarborane the equivalent activation energy is ca. 40 kJ mol-1 from the 1H spectrum.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 5350-41-4, molcular formula is C10H16BrN, introducing its new discovery. Quality Control of: N,N,N-Trimethyl-1-phenylmethanaminium bromide

The Mechanism of Photolysis of Some Benzyltrimethylammonium Salts in Water and in Alcohols

Photolysis of a range of benzyltrimethylammonium and 3,5-dimethoxybenzyltimethylammonium salts in water or methanol at 253.7 nm gave typically benzyl alcohols (or benzyl methyl ethers), toluenes, bibenzyls and isomers, and di- and tri-methylammonium salts.By detailed sensitisation and quenching experiments it was established that, in the photolysis of benzyltrimethylammonium bromide in aqueous t-butyl alcohol, benzyl t-butyl ether, benzyl alcohol, and some toluene were produced by a singlet pathway and bibenzyl by a triplet pathway.A general mechanistic scheme for all the photolyses studied is thus suggested.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

The important role of N,N,N-Trimethyl-1-phenylmethanaminium bromide

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STORAGE-STABLE ONE-COMPONENT POLYURETHANE PREPREGS AND SHAPED BODIES COMPOSED OF POLYURETHANE COMPOSITION THAT HAVE BEEN PRODUCED THEREFROM

The invention relates to storage-stable one-component (1K) polyurethane prepregs and to shaped bodies produced therefrom.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Discovery of N,N,N-Trimethyl-1-phenylmethanaminium bromide

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Shape-Selective Recognition of Quaternary Ammonium Chloride Ion Pairs

Synthetic receptors that recognize ion pairs are potentially useful for many technical applications, but to date there has been little work on selective recognition of quaternary ammonium (Q+) ion pairs. This study measured the affinity of a tetralactam macrocycle for 11 different Q+¡¤Cl- salts in chloroform solution. In each case, NMR spectroscopy was used to determine the association constant (Ka) and the structure of the associated complex. Ka was found to depend strongly on the molecular shape of Q+ and was enhanced when Q+ could penetrate the macrocycle cavity and engage in attractive noncovalent interactions with the macrocycle’s NH residues and aromatic sidewalls. The highest measured Ka of 7.9 ¡Á 103 M-1 was obtained when Q+ was a p-CN-substituted benzylic trimethylammonium. This high-affinity Q+¡¤Cl- ion pair was used as a template to enhance the synthetic yield of macrocyclization reactions that produce the tetralactam receptor or structurally related derivatives. In addition, a permanently interlocked rotaxane was prepared by capping the end of a noncovalent complex composed of the tetralactam macrocycle threaded by a reactive benzylic cation. The synthetic method provides access to a new family of rotaxanated ion pairs that can likely act as anion sensors, molecular shuttles, or transport molecules.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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pH-responsive viscoelastic fluid formed by cleavable sodium hexadecyl phthalate monoester alone

Viscoelastic fluids based on wormlike micelles have attracted significant attention over the past decades, but they are generally difficult to achieve by an anionic surfactant alone. Here, we have synthesized a cleavable anionic surfactant, sodium hexadecyl phthalate monoester (PAS16). Compared with common palmitic soap, PAS16 not only has a better water-solubility (lower Krafft temperature) and a stronger ability to aggregate (lower critical micelle concentration), but can also spontaneously form a worm-based viscoelastic fluid with of pH 10.20, without the need for additives. This can be mainly attributed to the insertion of benzene rings. It was observed that the presence of 2.4% hexadecyl phthalate monoester (PAS16-H) can further enhance the viscoelasticity, resulting in a maximum at pH 7.66. This viscoelastic fluid can be quickly switched between a gel-like fluid and a low-viscosity dispersion by reversibly changing the pH between alkali and acidic conditions, accompanied with a transition between PAS16 and PAS16-H. Furthermore, the gel-like fluid can be permanently transformed into a milky dispersion through irreversible hydrolysis of the ester bond at high pH. In addition, a solution of PAS16 is more tolerant to metal ions than common anionic surfactants, which is very important in practical applications.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI