Related Products of 91804-75-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.91804-75-0, Name is 1,10-Phenanthroline-5-carbaldehyde, molecular formula is C13H8N2O. In a Article,once mentioned of 91804-75-0
We report the syntheses of two new organotin sulfide clusters with heteroaromatic substituents.Aphenanthroline-functionalized tin sulfide cluster [(RPhenSn)4S6] (1; RPhen= CMe2CH2C(Me)N-NC(H)C12H7N2) and a bipyridyl-terminated cluster [(R4-bipySn)4S6] (2; R4-bipy= CMe2CH2C(Me)N-NC(H)-4-C10H7N2) were obtained from reactions of the hydrazone-functionalized organotin sulfide cluster [(RNSn)4S6] (RN= CMe2CH2C(Me)N-NH2) with 1,10-phenanthroline-5-carboxaldehyde or 2,2′-bipyridine-4-carbaldehyde.1and2were tested towards their capability of trapping metal ions by means of the terminal chelating ligands. The reaction of2with ZnCl2afforded the cluster compound [(R4-bipyZnCl2Sn)4S6] (5), in which four ZnCl2units are coordinated by the heteroaromatic organic groups. We discuss the structures and demonstrate the effect of ZnCl2trapping on optical absorption and luminescence properties.
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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI