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Is an organic electro-phosphorescent material, a preparation method OLED thereof, and an organic electrophosphorescent material comprising the compound. of Formula I, or Formula II, wherein the compound of Formula III is a red light-emitting material. and the compound of Formula I is a red light-emitting material, of the present invention. II. The organic electrophosphorescent material of the present invention is easily sublimated and dissolved III for mass production . The present invention provides an organic electrophosphorescent material having a structure represented by the following formula: OLED. The organic electrophosphorescent material of the present invention is advantageous; in terms of efficiency. OLED. (by machine translation)

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This invention relates to deuterated indolocarbazole compounds that are useful in electronic applications. It also relates to electronic devices in which the active layer includes such a deuterated compound.

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Metal catalyst and ligand design,
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A ring-opening diphosphination of methylene- and vinylcyclopropanes with tetraaryldiphosphines (Ar2P-PAr2) has been developed to afford the corresponding 1,3-diphenylphosphinopropane- and 1,3-diphenylphosphinopentane-type bidentate ligands, respectively. The reaction proceeds under bromine cation-initiated, visible-light-promoted photoredox catalysis at ambient temperature. Owing to the ready availability of functionalized diphosphines, the electronically diverse MeO- and CF3-substituted bidentate ligands are also easily prepared.

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The directed difluoroacetamidation of unactivated arenes and heteroarenes with bromodifluoroacetamides via visible-light photoredox catalysis has been efficiently achieved at room temperature. Broad utility of this transformation is presented, including electronically deficient heteroaromatic and aromatic systems. The mechanistic pathway of the difluoroacetamidation was discussed based on photoluminescence quenching, spin-trapping, and kinetic isotope effect experiments.

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The present invention discloses an organic iridium complex and its application, the complex is applied to the OLED light-emitting device manufacturing, can obtain a good device performance, the iridium complex as OLED light-emitting device of the light emitting layer doped material when in use, the current efficiency of the device, power efficiency and external quantum efficiency is greatly improved. The invention the iridium complex in the OLED light-emitting device in the application effect is good, it has good industrialization prospects. (by machine translation)

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Metal catalyst and ligand design,
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The present disclosure provides a photoelectric conversion element including a lower electrode, a photoelectric conversion layer, and an upper electrode in this order, wherein the photoelectric conversion layer includes a first organic compound and a second organic compound having a lower reduction potential than that of the first organic compound, the first organic compound has an emission lifetime of 1.1 ns or more in chloroform solution, and the first organic compound is an organic compound represented by Formula [1] according to claim 1, a fluoranthene derivative, or a metal complex.

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Metal catalyst and ligand design,
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Intramolecular energy transfer in heteroleptic red phosphorescent dopant materials with mixed ligand units in one molecule was studied. 1-phenylisoquinoline (piq) and phenylpyridine (ppy) moieties were introduced as ligands for Ir based phosphorescent dopants and light emission mechanism was investigated. Intramolecular energy transfer from ppy ligand to piq ligand resulted in pure red emission without any green emission from ppy. Current efficiency of red devices was improved from 4 to 4.8 cdA by using mixed ligand structures.

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Metal catalyst and ligand design,
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Twelve Ir(III) triscyclometalated compounds containing up to three azobenzene fragments on their structure have been synthesized based on photochromic 2-phenylpyridyl type ligands 1-4. These complexes are intended to study the possibility of transferring the photochromicity of the azobenzene fragment to the organometallic compound, and the effect of the substitution pattern, relative distance of the azobenzene to the metal centre, and number of azobenzenes on their properties.

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Metal catalyst and ligand design,
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Phosphorescent Pt(II) complexes based on phenylbenzoazole ligands were synthesized and their photophysical properties were investigated for OLEDs. Multilayered OLEDs devices using these complexes as emitters showed the efficient emissions, which are very sensitive to the structural and photophysical properties of Pt(II) complexes. In particularly, a device C using Pt(II) complex 2 based on phenylbenzoazole ligand as the dopant exhibited efficient emission with a luminous efficiency, a power efficiency, an external quantum efficiency, and CIE coordinates of 8.03 cd/A, 2.79 lm/W, 4.84% at 20 mA/cm2, and (0.63, 0.35) at 10.0 V, respectively.

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Metal catalyst and ligand design,
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A multicomponent sulfonylation of O-acyl oximes via iminyl radicals with the insertion of sulfur dioxide under photoredox catalysis is achieved. This multicomponent reaction of O-acyl oximes, potassium metabisulfite, alkenes, and nucleophiles under visible-light irradiation is efficient, giving rise to a range of sulfones in moderate to good yields. A broad reaction scope is presented with good functional group compatibility.

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Metal catalyst and ligand design,
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