In 2022,Cuesta, Virginia; Singh, Manish Kumar; Gutierrez-Fernandez, Edgar; Martin, Jaime; Dominguez, Rocio; de la Cruz, Pilar; Sharma, Ganesh D.; Langa, Fernando published an article in ACS Applied Materials & Interfaces. The title of the article was 《Gold(III) Porphyrin Was Used as an Electron Acceptor for Efficient Organic Solar Cells》.Product Details of 51364-51-3 The author mentioned the following in the article:
The widespread use of nonfullerene-based electron-accepting materials has triggered a rapid increase in the performance of organic photovoltaic devices. However, the number of efficient acceptor compounds available is rather limited, which hinders the discovery of new, high-performing donor:acceptor combinations. Here, the authors present a new, efficient electron-accepting compound based on a hitherto unexplored family of known mols.: Au porphyrins. The electronic properties of the electron-accepting Au porphyrin, named VC10, were studied by UV-visible spectroscopy and by cyclic voltammetry (CV) , revealing 2 intense optical absorption bands at 500-600 and 700-920 nm and an optical bandgap of 1.39 eV. Blending VC10 with PTB7-Th, a donor polymer, which gives rise to an absorption band at 550-780 nm complementary to that of VC10, enables the fabrication of organic solar cells (OSCs) featuring a power conversion efficiency of 9.24% and an energy loss of 0.52 eV. Hence, this work establishes a new approach in the search for efficient acceptor mols. for solar cells and new guidelines for future photovoltaic material design. The experimental process involved the reaction of Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Product Details of 51364-51-3)
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors.Product Details of 51364-51-3It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI