Discovery of 105-83-9

Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 105-83-9, molcular formula is C7H19N3, introducing its new discovery. Application In Synthesis of N1-(3-Aminopropyl)-N1-methylpropane-1,3-diamine

Polynuclear Gold(I) Complexes of Dendritic Amines: Formation of Terminal Tris<(triphenylphosphine)aurio(I)>ammonium Groups – N(AuPPh3)3<*>(1+)

The reactions of dendritic amines RN(CH2CH2CH2NH2)2 (R = Me, c-Hex, PhCH2) and N(CH2CH2NH2)3 with tris<(triphenylphosphine)aurio(I)>oxonium tetrafluoroborate (+)BF4(-) in THF yield species with terminal imido cluster groups -N(AuPPh3)3<*>(1+).The compounds have been obtained as stable crystalline solids in high yields and characterized by NMR spectroscopy as well as mass spectrometry and elemental analysis.The triply charged nonanuclear complex (3+) exhibits major changes in the 1H spectroscopic data and in the chemical properties as compared with compounds with dications (2+) (R = Me, c-Hex, PhCH2).Excessive auration to give hypercoordinated species has not been observed. – Keywords: Gold(I) Complexes, Dendritic Amines, Gold(I) Complexes, Primary Amines

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI