Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 119-91-5, Name is 2,2′-Biquinoline, SMILES is C1(C2=NC3=CC=CC=C3C=C2)=NC4=CC=CC=C4C=C1, in an article , author is Lu, Shuang, once mentioned of 119-91-5, Application In Synthesis of 2,2′-Biquinoline.
Tertiary phosphine disubstituted diiron bis(monothiolate) carbonyls related to the active site of [FeFe]-H(2)ases: Preparation, protonation and electrochemical properties
As biomimetic models of the active site of [FeFe]-H(2)ases, two electron-rich, PR3 -disubstituted diiron bis(monothiolate) carbonyls Fe-2 (mu-SBn)(2) (CO)(4)L-2 (Bn = CH2 Ph, L = PPhMe2 , 1; PMe3 , 2) have been prepared. To further mimic the structural and functional models for the protonated diiron subsite, the mu-hydride diiron compounds [(mu-H)Fe-2(mu-SBn)(2)(CO)(4)L-2] BF4 (L = PPhMe2, 1-H+; and PMe3, 2-H+) were prepared by protonation reactions of 1 and 2 with HBF4 center dot Et2O. All the compounds were characterized by elemental analysis, FT-IR, NMR spectroscopy, and particularly for 1, 2 and 2-H+ by X-ray diffraction analyses. Furthermore, the electrochemical properties of 1 and 2 are studied by cyclic voltammetry (CV) in MeCN, 1 has been found to be catalyst for H-2 production in the presence of acetic acid (HOAc).
Interested yet? Read on for other articles about 119-91-5, you can contact me at any time and look forward to more communication. Application In Synthesis of 2,2′-Biquinoline.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI