Application of 16858-01-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.16858-01-8, Name is Tris(2-pyridylmethyl)amine, molecular formula is C18H18N4. In a Article，once mentioned of 16858-01-8
Structure and magnetism of heptanuclear complex constructed by the encapsulation of octacyanotungstate(IV) with copper(II) cations of tripodal ligands
A new heptanuclear compound [{Cu(TPA)CN}6W(CN) 2][ClO4]8·14H2O (1) (TPA = tris(2-pyridylmethyl)amine) was synthesized by the reaction of [Cu(TPA)] 2 + unit and K4W(CN)8. The cyanometalate core is encapsulated by mononuclear copper moieties via cyano bridges. 1 crystallizes in monoclinic space group P21/c with a = 22.01(2) A?, b = 26.87(3) A?, c = 31.64(2) A?, beta = 128.87(2), and Z = 4. Variable temperature magnetic measurements have demonstrated that very weak ferromagnetic interaction between the nearest paramagnetic CuII centers is exhibited. Thus weak ferromagnetic coupling might be transferred by NCWCN bridging units.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI