Related Products of 6291-84-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 6291-84-5, Name is N-Methylpropane-1,3-diamine, SMILES is NCCCNC, belongs to catalyst-ligand compound. In a article, author is Mirdarvatan, Vahid, introduce new discover of the category.
A new vanadium complex having [OVV(mu-O)(2)(VO)-O-V] core with anti-coplanar configuration: Synthesis, crystal structure, DFT calculation, antibacterial and a homogeneous catalyst for epoxidation of alkenes
A new dinuclear vanadium(V) Schiff base complex [VO2(L)](2) with [OVV(mu-O)(2)(VO)-O-V] core was synthesized and characterized by FT-IR and H-1 NMR spectroscopy and single-crystal X-ray analysis. The X-ray structural analysis revealed a centrosymmetric structure with anti-coplanar configuration, consisting of two symmetry-independent complex parts. In each part, two edge sharing symmetry-related octahedral (VO)-O-V centers connected two ONN Schiff base ligands. Epoxidation of cis-cyclooctene was carried out in the presence of this complex, and the experimental procedures were optimized. The optimized experimental conditions were implemented and tested successfully for the epoxidation of some other substituted alkenes. Density functional theory (DFT) calculations were done to obtain the electronic and geometric structures of the complex. The in vitro antibacterial activity of the ligand (HL) and its corresponding vanadium(V) complex was evaluated against three gram-positive (S. aureus, E. faecalis, and B. cereus) and three gram-negative (P. aeruginosa, E. coli, and K. pneumoniae) bacterial strains. (C) 2020 Elsevier Ltd. All rights reserved.
Related Products of 6291-84-5, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 6291-84-5.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI