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A visible light-catalyzed trifluoromethyl substituted […] derivative synthesis method (by machine translation)
The invention discloses a visible light catalytic trifluoromethyl substituted […] derivative synthesis method, of formula (I) indicated by the alpha – carbonyl dithio keteal or its derivatives, Umemoto reagent, alkaline material and photocatalyst in the organic solvent is added, in a nitrogen atmosphere, visible light illumination, under normal temperature and stirring the reaction 15 – 30 h, the reaction solution obtained after treatment, as shown in formula (II) […] trifluoromethyl derivatives of; the method of the invention mild reaction conditions, the operation is simple, high selectivity, the yield is good, the substituents may be the expand; and adopts the visible photocatalytic, pollution-free, environment-friendly and the like, is a very promising method. (by machine translation)
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI