Electric Literature of 4062-60-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.4062-60-6, Name is N1,N2-Di-tert-butylethane-1,2-diamine, molecular formula is C10H24N2. In a Article£¬once mentioned of 4062-60-6
Mechanistic studies on au(I)-catalyzed [3,3]-sigmatropic rearrangements using cyclopropane probes
A comparative study of the Au(I)-catalyzed [3,3]-sigmatropic rearrangement of propargylic esters and propargyl vinyl ethers is described. Stereochemically defined cyclopropanes are employed as mechanistic probes to provide new synthetic and theoretical data concerning the reversibility of this type of rearrangement. Factors controlling the structure-reactivity relationship of Au(I)-coordinated allenes have been examined, therebyallowing for controlled access to orthogonal reactivity.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI