33454-82-9, Lithium trifluoromethanesulfonate is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
The binuclear ruthenium aqua complex was prepared byreacting [{RuCl(Clphen)}2(tpy2ph)](TfO)2 (50.0 mg, 0.03 mmol) in2mL of CF3SO3H (Trifluoromethanesulfonic acid) at room temperature,under stirring and inert atmosphere. After 3 h, the productwas precipitated out with an aqueous LiTfO solution, filtered usinga sintered glass filter and washed with cold diethyl ether, andfinally dried in a desiccator under vacuum. Yield: 38.0 mg (68%). 1HNMR (D2O:acetone-d6 (7:3) 500 MHz) delta (ppm) (m, J, H): 10.04 (d,J 5.1 Hz, 1H), 9.97 (d, J 5.2 Hz, 1H), 9.21 (s, 1H), 9.20 (s, 4H), 8.90(d, J 8.3 Hz, 2H), 8.77 (d, J 8.0 Hz, 4H), 8.56 (d, J 5.8 Hz, 2H),8.54 (d, J 3.1 Hz, 1H), 8.46 (dd, J 8.3, 5.2 Hz, 1H), 8.41 (d,J 8.2 Hz, 2H), 8.33 (s, 1H), 8.26 (d, J 8.4 Hz, 1H), 8.08 (t, J 7.8 Hz,1H), 8.03 (t, J 7.9 Hz, 4H), 7.95 (d, J 5.5 Hz, 1H), 7.87 (d, J 5.5 Hz,1H), 7.75 (d, J 5.6 Hz, 4H), 7.50 (dd, J 8.4, 5.5 Hz, 1H), 7.40 (dd,J 8.2, 5.5 Hz, 1H), 7.32e7.28 (m, 4H). C62H42Cl2F12N10O14S4-Ru25H2O (1894.43) calcd.%: C 40.58, H 2.77, N 7.39; found: C 40.70,H 2.61, N 7.81., 33454-82-9
33454-82-9 Lithium trifluoromethanesulfonate 3664839, acatalyst-ligand compound, is more and more widely used in various fields.
Reference£º
Article; Matias, Tiago A.; Parussulo, Andre L.A.; Benavides, Paola A.; Guimaraes, Robson R.; Dourado, Andre H.B.; Nakamura, Marcelo; de Torresi, Susana I. Cordoba; Bertotti, Mauro; Araki, Koiti; Electrochimica Acta; vol. 283; (2018); p. 18 – 26;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI