Extended knowledge of 2,4,6-Triphenylpyrylium tetrafluoroborate

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N-Substituents are transferred from pyridinium cations to malonate, cyanoacetate , and acetoacetate carbanions: for alkyl substituents the pentacyclic derivatives (4) attain the required activity.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI