Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , Recommanded Product: N,N,N-Trimethylhexadecan-1-aminium chloride, 112-02-7, Name is N,N,N-Trimethylhexadecan-1-aminium chloride, molecular formula is C19H42ClN, belongs to catalyst-ligand compound. In a document, author is Razgoniaev, Anton O., introduce the new discover.
Single-Molecule Activation and Quantification of Mechanically Triggered Palladium-Carbene Bond Dissociation
Metal-complexed N-heterocyclic carbene (NHC) mechanophores are latent reactants and catalysts for a range of mechanically driven chemical responses, but mechanochemical scission of the metal-NHC bond has not been experimentally characterized. Here we report the single-molecule force spectroscopy of ligand dissociation from a pincer NHC-pyridine-NHC Pd(II) complex. The force-coupled rate constant for ligand dissociation reaches 50 s(-1) at forces of approximately 930 pN. Experimental and computational observations support a dissociative, rather than associative, mechanism of ligand displacement, with rate-limiting scission of the Pd-NHC bond followed by rapid dissociation of the pyridine moiety from Pd.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 112-02-7. Recommanded Product: N,N,N-Trimethylhexadecan-1-aminium chloride.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI