Synthetic Route of 41203-22-9, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 41203-22-9, Name is 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane,introducing its new discovery.
Induced assembly of a catenated chain of edge-sharing silver(I) dodecahedra with embedded acetylide by silver(II)-tmc (tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)
In the mixed-valent complex [AgII(tmc)(BF4)][AgI6 (C2)-(CF3CO2)5(H2O)] ¡¤H2O, a [AgII(tmc)(BF4)]?+1 cationic column induces the assembly of a novel, anionic zigzag chain constructed from edge-sharing of silver(I) triangulated dodecahedra each enclosing a C22- species.
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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI