Application of 50446-44-1, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 50446-44-1, Name is 5′-(4-Carboxyphenyl)-[1,1′:3′,1”-terphenyl]-4,4”-dicarboxylic acid, molecular formula is C27H18O6. In a Article£¬once mentioned of 50446-44-1
Room temperature CO2 fixation via cyclic carbonate synthesis over vanadium-MOF catalysts
Vanadium containing 3D MOF, MIL-47 displayed excellent synergistic catalysis with alkyl ammonium halides (TBAX) in the room temperature fixation of CO2. Theoretical intrinsic-reaction-coordinate calculations were performed at the level of M06/LACVP**++ implemented in Jaguar v8.5 software to ascertain the mechanistic pathways of catalysis. A homogeneous complex of vanadium, vanadium acetyl acetonato [VO(acac)2], was used as a model system to investigate the mechanism behind the synergistic activity of the MIL-47/TBAX, which indeed shows that the activation energy of the CO2 fixation is considerably lowered by about 30?35 kcal compared to the uncatalyzed reactions.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Application of 50446-44-1, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 50446-44-1, in my other articles.
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI