A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Formula: C20H14O2, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18531-94-7, Name is (R)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a Article, authors is Maeda, Chihiro，once mentioned of 18531-94-7
A series of carbazole-based boron dipyrromethenes (BODIPYs) 2 a?g bearing binaphthyl units have been synthesized by the Et2AlCl-mediated reaction of the corresponding BODIPY difluorides 1 a?g with 1,1?-binaphthalene-2,2?-diol. Substituents such as halogen, nitrile, and amino groups were tolerated under the reaction conditions, and the reaction of the phenylethynyl-substituted 1 h gave (R,R)-3 h bearing two binaphthyl units. The chiroptical properties of these dyes with different substituents were investigated by UV/Vis, CD, fluorescence, and circularly polarized luminescence (CPL) spectroscopy. The CD spectra showed Cotton effects in the absorption region of the BODIPY moieties. In addition, they showed CPL both in solution and in the solid state. Interestingly, several dyes recorded higher glum values in the solid state, probably due to intermolecular interactions. Because (R,R)-3 h recorded relatively low glum values, the diastereomer (R,S)-3 h was prepared. The (R,S) diastereomer showed intense CPL, which suggests a synergetic effect of the two binaphthyl groups. Finally, chiral carbazole-based BODIPY dimers have been synthesized for the first time and their chiroptical properties were investigated. They showed redshifted fluorescence and CPL, which reached the near-IR (NIR) region in the solid state.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 18531-94-7, help many people in the next few years.Formula: C20H14O2
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI