The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.18531-99-2, Name is (S)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2, 18531-99-2, In a Article, authors is Taniguchi, Takahiko£¬once mentioned of 18531-99-2
Asymmetrization of a meso 1,2-enediol bis(trimethylsilyl) ether using a (S)-BINOL monoisopropyl ether(BINOL-Pr(i))-tin tetrachloride complex: An alternative route to (-)-ketodicyclopentadiene and (-)-ketotricyclononene
A tricyclic mesa 12-enediol bis(trimethylsilyl) ether having an endo-tricyclo[4.2.1.02,5]nonene framework has been asymmetrically desymmetrized by protonation with a complex generated from (S)-BINOL monoisopropyl ether (BINOL-Pr(i)) and tin tetrachloride to give the optically enriched acyloin in 90% ee. The chiral acyloin thus obtained has been transformed into two versatile chiral building blocks, (-)-ketodicyclopentadiene and (-)-ketotricyclononene, in optically pure forms via a sequence involving concurrent enzymatic acetylation and optical purification.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.18531-99-2. In my other articles, you can also check out more blogs about 18531-99-2
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI