Related Products of 49669-22-9, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.49669-22-9, Name is 6,6′-Dibromo-2,2′-bipyridine, molecular formula is C10H6Br2N2. In a Article，once mentioned of 49669-22-9
Various ruthenium(II) complexes with proximal oxophilic phenylselenium groups of the general formula [RuIILALB]X2{LA= LB= 6,6?-bis[(4-methoxyphenyl)selanyl]-2,2?-bipyridine; 6,6?-bis[(nitrophenyl)selanyl]-2,2?-bipyridine; 3,6-bis(phenylselanyl)dipyrido[3,2-a:2?,3?-c]phenazine; LA= 6,6?-bis(phenylselanyl)-2,2?-bipyridine, LB= terpyridine} were prepared. The substitution patterns of these compounds were designed to have different electron-withdrawing/-donating properties or different binding motifs in comparison to the previously reported compound with LA= LB= 6,6?-bis(phenylselanyl)-2,2?-bipyridine. The research objective was to evaluate the potential of these compounds to activate ground-state molecular oxygen to form higher-valent Ru?O?Se bonds by cleavage of the O?O bond of O2. All of the compounds prepared indeed activated O2to form Ru?O?Se moieties, as observable by UV/Vis spectroscopy, mass spectrometry, or X-ray crystallography.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI