Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, Application In Synthesis of MitMAB, 1119-97-7, Name is MitMAB, SMILES is CCCCCCCCCCCCCC[N+](C)(C)C.[Br-], belongs to catalyst-ligand compound. In a document, author is Tom, Lincy, introduce the new discover.
A 2D-layered Cd(II) MOF as an efficient heterogeneous catalyst for the Knoevenagel reaction
A Cd(II) coordination polymer based on a polytopic compartmental ligand was synthesized, and used as an efficient heterogeneous catalyst for the Knoevenagel reaction between benzaldehyde and malononitrile under mild reaction conditions. The solid catalyst was characterized using single crystal XRD, X-ray powder diffraction, SEM, TGA, UV diffuse reflectance, infrared spectroscopy and elemental analysis. The compound is a two-dimensional (2D) MOF with a grid structure. Topological analysis of the framework revealed that it is a 2,4-connected binodal net. The catalytic activity was tested between various benzaldehydes containing different substituents with malononitrile. The effect of reaction parameters such as solvent, time, reactant ratio and catalyst amount was investigated. Furthermore, the catalyst stability was examined through reusability experiments and it is observed that the catalyst can be recycled at least five times without significant drop in its activity.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1119-97-7. Application In Synthesis of MitMAB.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI