Synthetic Route of C11H21BrO2. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 11-Bromoundecanoic acid, is researched, Molecular C11H21BrO2, CAS is 2834-05-1, about Redox Control of Particle Deposition from Drying Drops. Author is Galy, Pauline E.; Guitton-Spassky, Tiffany; Sella, Catherine; Thouin, Laurent; Vitale, Maxime R.; Baigl, Damien.
The coffee-ring effect (CRE), which denotes the accumulation of nonvolatile compounds at the periphery of a pinned sessile drying drop, is a universal and ubiquitous yet complex phenomenon. It is crucial to better understand and control it, either to avoid its various deleterious consequences in many processes requiring homogeneous deposition or to exploit it for applications ranging from controlled particle patterning to low cost diagnostics. Here, we report for the first time the use of a reduction-oxidation (redox) stimulus to cancel the CRE or harness it, leading to a robust and tunable control of particle deposition in drying sessile drops. This is achieved by implementing redox-sensitive ferrocenyl cationic surfactants of different chain lengths in drying drops containing anionic colloids. Varying surfactant hydrophobicity, concentration, and redox state allows us not only to control the overall distribution of deposited particles, including the possibility to fully cancel the CRE, but also to modify the microscopic organization of particles inside the deposit. Notably, with all other parameters being fixed, this method allows the adjustment of the deposited particle patterns, from polycrystalline rings to uniform disks, as a function of the oxidation rate. We show that the redox control can be achieved either chem. by the addition of oxidants or electrochem. by applying a potential for additive-free and reversible actuation in a closed system. This correlation between the redox state and the particle pattern opens a perspective for both redox-programmable particle patterning and original diagnostic applications based on the visual determination of a redox state. It also contributes to clarify the role of surfactant charge and its amphiphilic character in directing particle deposition from drying suspensions.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI