In 2019,Organic Letters included an article by Hu, Xiao-Qiang; Lichte, Dominik; Rodstein, Ilja; Weber, Philip; Seitz, Ann-Katrin; Scherpf, Thorsten; Gessner, Viktoria H.; Goossen, Lukas J.. Product Details of 51364-51-3. The article was titled 《Ylide-Functionalized Phosphine (YPhos)-Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides》. The information in the text is summarized as follows:
In the presence of the ylide-functionalized YPhos phosphines Cy3P+C-MePR3 (R = Cy, t-Bu; Cy = cyclohexyl) and either Pd(cod)Cl2 or Pd2(dba)3, acyclic and cyclic ketones underwent chemoselective monoarylation with aryl chlorides at ambient temperature or 60° to yield monoarylated ketones such as 2-(4-methylphenyl)cyclohexanone. The crystal structure of Cy3P+C-MePt-Bu3 and of its (dibenzylideneacetone)palladium complex were determined by X-ray crystallog. The experimental part of the paper was very detailed, including the reaction process of Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Product Details of 51364-51-3)
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is the most widely used PdO precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. Product Details of 51364-51-3 It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI