In an article, author is Zheng, Zhipeng, once mentioned the application of 80875-98-5, Application In Synthesis of H-Oic-OH, Name is H-Oic-OH, molecular formula is C9H15NO2, molecular weight is 169.22, MDL number is MFCD07782125, category is catalyst-ligand. Now introduce a scientific discovery about this category.
Efficient Synthesis of Bulky 2,2 ‘-Bipyridine and (S)-Pyridine-Oxazoline Ligands
Bulky N,N’-bidentate ligands can furnish catalysts with enhanced catalytic activity compared to commercially available ligands. Straightforward methods to effectively synthesize a broad range of these ligands, however, are uncommon. In this work, a simple and efficient method is developed for the synthesis of bulky N,N’-bidentate ligands, including 2,2′-bipyridines and enantioenriched pyridine-oxazolines. The Pd/NIXANTPHOS catalyst system enabled synthesis of a series of bulky 2,2′-bipyridine-based ligands and (S)-pyridine oxazoline-based enantioenriched ligands with good to excellent yields. The ligands have been benchmarked in the aminofluorination of styrene.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI