In 2022,Karpov, G. O.; Bermeshev, M. V. published an article in Russian Journal of Applied Chemistry. The title of the article was 《Addition Polymerization of Cyclopentadiene in the Presence of Catalytic Systems Based on Pd(0) Complexes and Organic Cocatalysts》.Related Products of 51364-51-3 The author mentioned the following in the article:
Addition polymerization of cycloalkenes (cyclopentene, cyclopentadiene, cyclooctene, cyclooctadiene) in the presence of a new type of catalytic systems-Pd(0) complexes activated with arendiazonium salts-was studied. It was shown that cyclopentene, cyclooctene, and cyclooctadiene are not active in polymerization with these catalytic systems, while cyclopentadiene is actively involved in polymerization The polycyclopentadiene structure was confirmed by 1H NMR spectroscopy. The mol. weight parameters and microstructure of the polymer were determinedTris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Related Products of 51364-51-3) was used in this study.
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is the most widely used PdO precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. Related Products of 51364-51-3 It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI