Synthetic Route of 3153-26-2, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 3153-26-2, Name is Vanadyl acetylacetonate, molecular formula is C10H14O5V. In a Article,once mentioned of 3153-26-2
Treatment of Boc-protected (S)-serine (Ser) methyl ester with triphenylphosphine bromide Ph3PBr (intermittently generated from PPh3 and N-bromosuccinimide) yields Boc-3-bromoalanine (R)-Boc-BrAlaMe and, after deprotection, bromoalanine methyl ester (R)-BrAlaMe in the form of its hydrobromide. Boc-BrAlaMe and BrAlaMe have been structurally characterised. The reaction between BrAlaMe, salicylaldehyde (sal) and VO 2+ results in the formation of Schiff base complexes of composition [VO(sal-BrAlaMe)solv]+ (solv = CH3OH: 3, THF: 5) and [VO(sal-BrAla)THF] 4. DFT calculations of the structures of 3, 4 and 5, based on the B3LYP functional and employing the triple zeta basis set 6-311++g(d,p), provide distances Br…V = 4.0 ± 0.1 A, if some distortion of the dihedral angle ?N-C-C-Br is allowed (affording a maximum energy of ca. 45 kJ mol-1), and thus model Br…V distances detected by X-ray methods in bromoperoxidases from the marine algae Ascophyllum nodosum and Corallina pilulifera. The DFT calculations have been validated by comparing calculated and found structures, including the new complex [V VO(Amp-sal)OMe(MeOH)] (1, Amp is the aminophenol moiety) and the known complex [VO(l-Ser-van)H2O] (van = vanillin). Additional validation has been undertaken by checking experimental against calculated (BHandHLYP) EPR spectroscopic hyperfine coupling constants. Complexes containing bromine as a substituent at the phenyl moiety of a Schiff base ligand do not allow for an appropriate simulation of the Br…V distance in peroxidases. The closest agreement, d(Br…V) = 4.87 A, is achieved with [VO(3Br-salSer)THF] (6), where 3Brsal-Ser is the dianionic Schiff base formed between 3-Br-5-NO2-salicylaldehyde and serine.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Synthetic Route of 3153-26-2, you can also check out more blogs about3153-26-2
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI