Reference of 96556-05-7, Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 96556-05-7, Name is 1,4,7-Trimethyl-1,4,7-triazonane, SMILES is C1CN(CCN(CCN1C)C)C, belongs to catalyst-ligand compound. In a article, author is Vinoth, Govindasamy, introduce new discover of the category.
Catalytic conversion of 2,4,5-trisubstituted imidazole and 5-substituted 1H-tetrazole derivatives using a new series of half-sandwich (eta(6)-p-cymene) Ruthenium(II) complexes with thiophene-2-carboxylic acid hydrazone ligands
A new series of half-sandwich (eta(6) -p-cymene) ruthenium(II) complexes with thiophene-2-carboxylic acid hydrazide derivatives [Ru(eta(6) -p-cymene)(Cl)(L)] [L = N’-(naphthalen-1-ylmethylene)thiophene-2-carbohydrazide (L-1), N’-(anthracen-9-ylmethylene)thiophene-2-carbohydrazide (L-2 ) and N’-(pyren-1-ylmethylene)thiophene-2-carbohydrazide (L-3)] were synthesized. The ligand precursors and their Ru(II) complexes (1-3) were structurally characterized by spectral (IR, NMR and mass spectrometry) and elemental analysis. The molecular structures of the ruthenium(II) complexes 1-3 were determined by single-crystal X-ray diffraction. All complexes were used as catalysts for the one-pot three-component syntheses of 2,4,5-trisubstitued imidazole and 5-substituted 1H-tetrazole derivatives. The catalytic studies optimized parameters as solvent, temperature and catalyst. The catalysts revealed very active for a broad range of aromatic aldehydes presenting either electron attractor or electron donor substituents and, although less active, moderate to high activities were observed for alkyl aldehydes.
Reference of 96556-05-7, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 96556-05-7.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI