Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Nechmad, Noy B., once mentioned the application of 206996-60-3, Name is Cerium(III) acetate xhydrate, molecular formula is C6H11CeO7, molecular weight is 335.2633, MDL number is MFCD00150533, category is catalyst-ligand. Now introduce a scientific discovery about this category, Application In Synthesis of Cerium(III) acetate xhydrate.
Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
This Account summarizes the historical development of latent sulfur-chelated ruthenium precatalysts from the Lemcoff group’s perspective. The most unique feature of this family of complexes is that they appear in the more stable cis-dichloro configuration, which is latent towards olefin metathesis reactions. Activation of the precatalyst, brought about by isomerization from the cis-dihalo to the trans-dihalo forms, can be achieved either by thermal or light stimuli. Modifications of the ligand sphere bestows unique properties upon the catalysts, which have been used in diverse applications, from 3D printing of metathesis polymers to orthogonally divergent synthetic pathways. Introduction Effect of Sulfur Substituents Effect of Benzylidene Ligands Effect of the NHC Ligands Effect of the Anionic Ligands Conclusions
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI