Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 1271-19-8, molcular formula is C10Cl2Ti, introducing its new discovery. SDS of cas: 1271-19-8
The Cp2*TiAlH4 complexes (Cp* = Cp, MeCp, Me3CP, Me4CP, Me5CP and EtMe4Cp) were prepared from Cp2*TiCl and LiAlH4 in toluene.On aging, all the Cp2*TiAlH4 complexes, except for the peralkylated ones, formed paramagnetic clusters composed probably of the Cp2*TiH and Cp2*TiAlH4 units.The clusters reacted with an excess of butadiene to give (1-methyl-eta3-allyl)titanocenes and Cp2*TiAlH4 complexes.The Cp2*TiAlH4 complexes yielded the same allyltitanocene products, but in a slower subsequent reaction.Aging of the peralkylated Cp2*TiAlH4 complexes led to the thus far unknown paramagnetic products which are unreactive to butadiene.The (1-methyl-eta3-allyl)titanocenes were also prepared from Cp2*TiCl by reaction with LiAlH4 in the toluene/butadiene mixture.The Cp2*TiAlH4 complexes which formed transiently in these systems were found to have ESR parameters different from those obtained in pure toluene.The effects were established of the methyl substituents in the Cp* ligands on the ESR and electronic absorption spectra of the Cp2*TiAlH4 complexes and (1-methyl-eta3-allyl)titanocenes.
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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI