Application of 344-25-2, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 344-25-2, Name is H-D-Pro-OH, SMILES is O=C(O)[C@@H]1NCCC1, belongs to catalyst-ligand compound. In a article, author is Ullah, Saif, introduce new discover of the category.
Quantitative Determination of Kaempferol by using a novel B-Z Chemical Oscillating system Catalyzed by a Cu (II)-tetraazamacrocyclic Complex
An appropriate analytical technique for determination of kaempferol (KMF) by its perturbation effect on Belousov-Zhabotinskii (B-Z) oscillating system was reported. The macrocyclic copper (II) complex [CuL] (ClO4)(2)] was used as a catalyst while malic acid as substrate in B-Z system. The ligand L in the macrocyclic-complex is 5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 11-diene. Experimental outcomes shown the perturbation effect of KMF could cause the change in the amplitude of oscillation (Delta A) which was directly related to its concentration (2.5 x 10(-6) to 3.0 x 10(-4) mol/L) with correlation coefficient of 0.99315. The calculated relative standard deviation (RSD) is 3.1 % by eight samples (1.8 x 10(-5) mol/L) and the observed lower limit of detection is 1.25 x 10(-6) mol/L. The cyclic voltammetry (CV) experiments were used to confirm the redox reaction between kaempferol and sodium bromate. Furthermore, the reaction perturbation mechanism was derived from the well-known FKN (Field-Koros-Noyes) oscillation mechanism.
Application of 344-25-2, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 344-25-2 is helpful to your research.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI