112881-51-3, 4′-(4-Pyridyl)-2,2′:6′,2”-terpyridine is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: [Ru(1)(3)](PF6)2 was prepared according to the literature procedure.[16] Ru(1)Cl3 (0.10 g, 0.19 mmol) and ligand 3 (0.06 g,0.19 mmol) were suspended in ethane-1,2-diol (10 mL) and heated at reflux for 2 h. The red solution was cooled to room temperature and excess aqueous KPF6 was added. The resulting red precipitate was collected on Celite, dissolved in acetonitrile,and purified by column chromatography (SiO2, MeCN/H2O/saturated aqueous KNO3 14 : 1.2 : 0.5). The main red band was collected, excess aqueous KPF6 was added, and the solvent volume reduced to give a fine red precipitate, which was collected on Celite and washed with water (20 mL), ethanol (10 mL), and diethyl ether (20 ml). The residue was dissolved in MeCN and the solvent removed to give [Ru(1)(3)](PF6)2 as a red powder (0.07 g, 0.07 mmol, 36 %).
112881-51-3, As the paragraph descriping shows that 112881-51-3 is playing an increasingly important role.
Reference£º
Article; Iranmanesh, Hasti; Arachchige, Kasun S. A.; Donald, William A.; Kyriacou, Niamh; Shen, Chao; Price, Jason R.; Beves, Jonathon E.; Australian Journal of Chemistry; vol. 70; 5; (2017); p. 529 – 537;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI