13104-56-8, 4′-(4-Methoxyphenyl)-2,2′:6′,2”-terpyridine is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
13104-56-8, 4,4?-bipyridine (23mg, 0.15 mmol) and atpy (51 mg, 0.15 mmol) in CH2Cl2 was added to a solution of Cu(CH3COO)2¡¤H2O (30 mg, 0.15 mmol) in methanol (15 mL). After stirring for 10min, an excess of NH4PF6 (60 mg, 0.37 mmol) was added to solution. The reaction mixture was then stirred for 2 h. The solvent was removed at reduced pressure and the green residue was precipitated using diethyl ether. Yield: 32mg, 31%; m.p. 233-235 C (dec.). Anal. Calc. for C58H48Cu2F12N8O6P2¡¤1.5H2O. CH2Cl2: C, 47.72; H, 3.54; N, 7.42. Found: C, 47.26; H, 3.03; N, 7.99%. TGA-DTA: calc. by formula C58H48Cu2F12N8O6P2¡¤0.5H2O: H2O%=0.64, 2(CH3COO)%=8.44, 4,4?-bpy%=12.18, Cu(CH3COO)2%=16.18. Determined H2O%=0.71, 2(CH3COO)%=6.15, 4,4?-bpy%=12.81, Cu(CH3COO)2%=16.91. IR data (KBr, cm-1): 3389, 3055, 1598, 1470, 1407, 1243, 1189, 1019, 835, 794, 688, 641, 586, 519. Green crystals of 3 were obtained from a MeOH/diethyl ether solution.
The synthetic route of 13104-56-8 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Momeni, Badri Z.; Heydari, Sepideh; Polyhedron; vol. 97; (2015); p. 94 – 102;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI