76089-77-5,76089-77-5, Cerium(III) trifluoromethanesulfonate is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
Example 7The above-described ligand represented by formula (B-13) (50 mg, 0.062 mmol) and cerium trifluoromethanesulfonate (35 mg, 0.060 mmol) were charged into a flask. Then, ethanol (5 mL) was added thereto and dissolved. The mixed solution was stirred for 2 hours at room temperature, and then the stirring was stopped. About 20 mL of diethyl ether was added, and the resultant mixture was left to stand overnight. After that, the produced solid was collected to obtain the above-described metal complex represented by composition formula (C-13) (hereinafter, ?metal complex (C-13)?). The collected amount was 41 mg (yield 43%).Elemental analysis: Found (%) C, 45.67; H, 4.71; N, 9.93; S, 6.54. Calcd for C53H62CeF9N10O9S3 (%) C, 45.78; H, 4.49; N, 10.07; S, 6.92.The metal complex (C-13) emitted a blue color in a solid powder state and in a solution state (acetonitrile) under ultraviolet excitation (365 nm).The emission spectrum in acetonitrile had a peak at 428.5 nm, the emission quantum yield was 25%, and the excitation life was 56 ns.
76089-77-5 Cerium(III) trifluoromethanesulfonate 2733941, acatalyst-ligand compound, is more and more widely used in various fields.
Reference£º
Patent; SUMITOMO CHEMICAL COMPANY, LIMITED; US2012/211706; (2012); A1;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI