Application of 147-85-3, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 147-85-3, Name is H-Pro-OH, SMILES is O=C(O)[C@H]1NCCC1, belongs to catalyst-ligand compound. In a article, author is Murai, Takuya, introduce new discover of the category.
Conformational Control in Dirhodium(II) Paddlewheel Catalysts Supported by Chalcogen-Bonding Interactions for Stereoselective Intramolecular C-H Insertion Reactions
D-2-symmetric dirhodium(II) carboxylate catalysts that bear axially chiral binaphthothiophene delta-amino acid derivatives have been developed. Conformational control is supported through chalcogen-bonding interactions between sulfur and oxygen atoms in each ligand, providing well-defined and uniform asymmetric environments around the catalytically active Rh(II) centers. These structural properties make such complexes asymmetric catalysts for the stereoselective intramolecular C-H insertion into alpha-aryl-alpha-diazoacetates to yield a variety of cis-alpha,beta-diaryl gamma-lactones, as well as the corresponding trans-isomers through epimerization, in high diastereo- and enantioselectivities. Short total syntheses of the naturally occurring gamma-lactones, cinnamomumolide, cinncassin A(7), and cinnamomulactone were also accomplished using this conformationally controlled catalyst.
Application of 147-85-3, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 147-85-3 is helpful to your research.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI