So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bonneau, Guillaume; Peru, Aurelien A. M.; Flourat, Amandine L.; Allais, Florent researched the compound: (S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one( cas:32780-06-6 ).Quality Control of (S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one.They published the article 《Organic solvent- and catalyst-free Baeyer-Villiger oxidation of levoglucosenone and dihydrolevoglucosenone (Cyrene): a sustainable route to (S)-γ-hydroxymethyl-α,β-butenolide and (S)-γ-hydroxymethyl-γ-butyrolactone》 about this compound( cas:32780-06-6 ) in Green Chemistry. Keywords: catalyst Baeyer Villiger oxidation levoglucosenone Cyrene hydroxymethylbutenolide hydroxymethylbutyrolactone. We’ll tell you more about this compound (cas:32780-06-6).
A straightforward and sustainable route to (S)-γ-hydroxymethyl-α,β-butenolide (HBO) and (S)-γ-hydroxymethyl-α,β-butyrolactone (2H-HBO), two valuable chem. platforms for the synthesis of fine chems. such as drugs, pheromones, flavors and fragrances, has been optimized using renewable cellulose-based levoglucosenone (LGO) and Cyrene as starting materials and aqueous H2O2 as both a solvent and an oxidizing agent. Combined with short-path distillation, this procedure provides enantiopure HBO and 2H-HBO in yield as high as 72% at the kilo scale.
If you want to learn more about this compound((S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one)Quality Control of (S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(32780-06-6).
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI