Properties and Exciting Facts About 1,10-Phenanthroline-4,7-diol

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 3922-40-5 is helpful to your research. Application of 3922-40-5

Application of 3922-40-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3922-40-5, Name is 1,10-Phenanthroline-4,7-diol, molecular formula is C12H8N2O2. In a Article,once mentioned of 3922-40-5

Water oxidation is traditionally performed over IrO2 and RuO2 owing to their high stability at low pH compared to molecular O2 evolution catalysts. The low stability of molecular complexes in acids limits their industrial exploitation as anodes in water-splitting devices, where high current densities and proton conductivity are required. Herein, an existing Co(1,10-phenanthroline)2 complex film is engineered to improve its pH-stability via extra OH substituents on the ligand, i.e. 1,10-phenanthroline-4,7-diol. This novel Co(1,10-phenanthroline-4,7-diol)2 complex film is active for water oxidation at low overpotentials and stable at low pH. Since the calculated water oxidation overpotentials of both complexes are similar, the difference in water oxidation activity is attributed to a smaller charge transfer resistance, which originates from a different anchoring style to the electrode via the OH groups of the ligand. This result is supported by electrochemical impedance measurements. The high pH-stability of the Co(1,10-phenanthroline-4,7-diol)2 film is computationally rationalized by a high crystal formation energy observed in DFT calculations. In summary, an acid-stable and active cobalt-based metal-organic film is reported that competes well with most reported earth-abundant catalysts for water oxidation under similar conditions.

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 3922-40-5 is helpful to your research. Application of 3922-40-5

Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI